#!/usr/bin/env python
# encoding: utf-8

name = "primaryH2O2"
shortDesc = u"primaryH2O2"
longDesc = u"""
Based on:
[Konnov2015] A.A. Konnov, "On the role of excited species in hydrogen combustion", Combustion and Flame 2015, 
162, 3755-3772, DOI: 10.1016/j.combustflame.2015.07.014
[Konnov2019] A.A. Konnov, "Yet another kinetic mechanism for hydrogen combustion", Combustion and Flame 2019, 
203, 14-22, DOI: 10.1016/j.combustflame.2019.01.032 
"""

entry(
    index = 1,
    label = "H + H <=> H2",
    kinetics = ThirdBody(
        arrheniusLow=Arrhenius(A=(7e+17, 'cm^6/(mol^2*s)', '*|/', 2), n=-1.0, Ea=(0, 'cal/mol'), T0=(1, 'K'),
                               Tmin=(77, 'K'), Tmax=(5000, 'K')),
        efficiencies={'[Ar]': 0.0, '[He]': 0.0, 'N#N': 0.0, '[H]': 0.0, '[H][H]': 0.0, '[O][O]': 0.0, 'O': 14.3}),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 1a""",
)

entry(
    index = 2,
    label = "H + H + O2 <=> H2 + O2",
    kinetics = Arrhenius(A=(8.80e+22, 'cm^6/(mol^2*s)', '*|/', 2), n=-1.835, Ea=(800, 'cal/mol'), Tmin=(300, 'K'),
                         Tmax=(3000, 'K')),
    shortDesc = u"""[Konnov2019]""",
    longDesc = u"""Konnov (2019) https://doi.org/10.1016/j.combustflame.2019.01.032, Table 1, Reaction 1""",
)

entry(
    index = 3,
    label = "H2 + Ar <=> H + H + Ar",
    kinetics = Arrhenius(A=(5.84e+18, 'cm^3/(mol*s)'), n=-1.10, Ea=(104380, 'cal/mol'), T0 = (1, 'K')),
    shortDesc = u"""Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)""",
)

entry(
    index = 4,
    label = "H2 + He <=> H + H + He",
    kinetics = Arrhenius(A=(5.84e+18, 'cm^3/(mol*s)'), n=-1.10, Ea=(104380, 'cal/mol'), T0 = (1, 'K')),
    shortDesc = u"""Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)""",
)

entry(
    index = 5,
    label = "H + H + H2 <=> H2 + H2",
    kinetics = Arrhenius(A=(1e+17, 'cm^6/(mol^2*s)', '*|/', 2.5),n=-0.6, Ea=(0, 'cal/mol'), T0=(1, 'K'),
                         Tmin=(50, 'K'), Tmax=(5000, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 1b""",
)

entry(
    index = 6,
    label = "H + H + N2 <=> H2 + N2",
    kinetics = Arrhenius(A=(5.4e+18, 'cm^6/(mol^2*s)', '*|/', 3.2), n=-1.3, Ea=(0, 'cal/mol'), T0=(1, 'K'),
                         Tmin=(77, 'K'), Tmax=(2000, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 1c""",
)

entry(
    index = 7,
    label = "H + H + H <=> H2 + H",
    kinetics = Arrhenius(A=(3.2e+15, 'cm^6/(mol^2*s)', '*|/', 3.2), n=0, Ea=(0, 'cal/mol'), T0=(1, 'K'), Tmin=(50, 'K'),
                         Tmax=(5000, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 1d""",
)

entry(
    index = 8,
    label = "H + O2 + H <=> OH + OH",
    kinetics = Arrhenius(A=(4.00e+22, 'cm^6/(mol^2*s)', '*|/', 2), n=-1.835, Ea=(800, 'cal/mol'), Tmin=(300, 'K'),
                         Tmax=(3000, 'K')),
    shortDesc = u"""[Konnov2019]""",
    longDesc = u"""Konnov (2019) https://doi.org/10.1016/j.combustflame.2019.01.032, Table 1, Reaction 2""",
)

entry(
    index = 9,
    label = "O + H <=> OH",
    kinetics = ThirdBody(
        arrheniusLow=Arrhenius(A=(6.75e+18, 'cm^6/(mol^2*s)'), n=-1, Ea=(0, 'cal/mol'), T0=(1, 'K'), Tmin=(2950, 'K'),
                         Tmax=(3700, 'K')),
        efficiencies={'O': 5.0, '[H][H]': 2.5, '[C-]#[O+]': 1.9, 'O=C=O': 3.8, '[Ar]': 0.75, '[He]': 0.75, '[O][O]': 0.0}),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 3
    The efficiency for H2O was taken from Konnov 2015, other collider efficiencies were taken from Curran 10.1016/j.combustflame.2015.09.014
    Note that in the Curran library th efficiency for O2 was 12, her for consistency we remain with
    the Konnov recommendation of collision efficiency for O2 of 5.
    """,
)

entry(
    index = 10,
    label = "H + O + O2 <=> OH + O2",
    kinetics = Arrhenius(A=(7.35e+22, 'cm^6/(mol^2*s)', '*|/', 2), n=-1.835, Ea=(800, 'cal/mol'), Tmin=(300, 'K'),
                         Tmax=(3000, 'K')),
    shortDesc = u"""[Konnov2019]""",
    longDesc = u"""Konnov (2019) https://doi.org/10.1016/j.combustflame.2019.01.032, Table 1, Reaction 3""",
)

entry(
    index = 11,
    label = "H2O <=> H + OH",
    kinetics = ThirdBody(
        arrheniusLow=Arrhenius( A=(6.06e+27, 'cm^3/(mol*s)'), n=-3.312, Ea=(120770, 'cal/mol'), T0=(1, 'K'),
                        Tmin=(300, 'K'), Tmax=(3400, 'K')),
        efficiencies={'N#N': 2.0, 'O': 0.0, '[H][H]': 3.0, '[He]': 1.1, '[O][O]': 0.0, '[C-]#[O+]': 1.9, 'O=C=O': 3.8}),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 4a
    Note that in Konnov2015 the collision efficiency for O2 was 1.5, but Konnov2019 updated the rate
    for the specific collider (see reaction index 13). THerefore, an efficiency of 0 was given here for O2.""",
)

entry(
    index = 12,
    label = "H2O + H2O <=> H + OH + H2O",
    kinetics = Arrhenius(A=(1e+26, 'cm^3/(mol*s)'), n=-2.44, Ea=(120160, 'cal/mol'), T0=(1, 'K'), Tmin=(300, 'K'),
                    Tmax=(3400, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 4b
                   Originally from Srinivasan and Michael, Int. J. Chem. Kinetic 38 (2006)""",
)

entry(
    index = 13,
    label = "H + OH + O2 <=> H2O + O2",
    kinetics = Arrhenius(A=(2.56e+22, 'cm^6/(mol^2*s)', '*|/', 2), n=-1.835, Ea=(800, 'cal/mol'), Tmin=(300, 'K'),
                         Tmax=(3000, 'K')),
    shortDesc = u"""[Konnov2019]""",
    longDesc = u"""Konnov (2019) https://doi.org/10.1016/j.combustflame.2019.01.032, Table 1, Reaction 4""",
)

entry(
    index = 14,
    label = "H + O2 <=> HO2",
    kinetics = Troe(
        arrheniusHigh = Arrhenius(A=(4.66e+12, 'cm^3/(mol*s)', '*|/', 1.2), n=0.44, Ea=(0, 'cal/mol'), Tmin=(300, 'K'),
                                  Tmax=(2000, 'K')),
        arrheniusLow = Arrhenius(A=(1.225e+19, 'cm^6/(mol^2*s)', '*|/', 1.2), n=-1.2, Ea=(0.0, 'cal/mol'),
                                 Tmin=(1000, 'K'), Tmax=(1430, 'K')), T3=(1752, 'K'), T1=(1e-10, 'K'), T2=(1e+30, 'K'),
        efficiencies = {'[H][H]': 1.5, 'O=C=O': 3.61, '[He]': 0.57, '[Ar]': 0.72, 'O': 16.6},),
    shortDesc = u"""[Konnov2019]""",
    longDesc = u"""Konnov (2019) https://doi.org/10.1016/j.combustflame.2019.01.032, Table 1, Reaction 6
                   The value of T3 was calculated with the first factor of the Lindemann model and an Fcent 
                   value of 0.5 specified in the Konnov 2019 paper.""",
)

entry(
    index = 15,
    label = "H + O2 <=> OH + O",
    kinetics = Arrhenius(A=(1.04e+14, 'cm^3/(mol*s)'), n=0, Ea=(15286, 'cal/mol'), T0=(1, 'K'), Tmin=(1100, 'K'),
                         Tmax=(3370, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 8
                   Originally based on Hong et al., Proc. Comb. Inst. 33:309-316 (2011)""",
)

entry(
    index = 16,
    label = "OH + OH <=> H2O + O",
    kinetics = Arrhenius(A=(2.668e+06,'cm^3/(mol*s)', '*|/', 1.4), n=1.82, Ea=(-1647, 'cal/mol'), T0=(1, 'K'),
                         Tmin=(200, 'K'), Tmax=(2000, 'K')),
    shortDesc = u"""[Konnov2019]""",
    longDesc = u"""Konnov (2019) https://doi.org/10.1016/j.combustflame.2019.01.032, Table 1, Reaction 5""",
)

entry(
    index = 17,
    label = "OH + HO2 <=> H2O + O2",
    kinetics = Arrhenius(A=(2.14e+06, 'cm^3/(mol*s)', '*|/', 2), n=1.65, Ea = (2180, 'cal/mol'), Tmin=(200, 'K'),
                         Tmax=(2500, 'K')),
    shortDesc = u"""[Konnov2019]""",
    longDesc = u"""Konnov (2019) https://doi.org/10.1016/j.combustflame.2019.01.032, Table 1, Reaction 7""",
)

entry(
    index = 18,
    label = "O + O <=> O2",
    kinetics = ThirdBody(
        arrheniusLow=Arrhenius(A=(1e+17, 'cm^6/(mol^2*s)'), n=-1, Ea=(0, 'cal/mol'), T0=(1, 'K'), Tmin=(300, 'K'),
                         Tmax=(5000, 'K')),
        efficiencies={'[Ar]': 0.0, '[He]': 0.0, 'N#N': 2.0, '[N]=O': 2.0, '[N]': 2.0, 'O': 5.0, '[O-][O+]=O': 8.0,
                      '[O]': 28.8, '[O][O]': 8.0}),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 2""",
)

entry(
    index = 19,
    label = "O + O + Ar <=> O2 + Ar",
    kinetics = Arrhenius(A=(1.886e+13, 'cm^6/(mol^2*s)'), n=0, Ea=(-1788, 'cal/mol'), T0 = (1, 'K')),
    shortDesc = u"""Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)""",
)

entry(
    index = 20,
    label = "O + O + He <=> O2 + He",
    kinetics = Arrhenius(A=(1.886e+13, 'cm^6/(mol^2*s)'), n=0, Ea=(-1788, 'cal/mol'), T0 = (1, 'K')),
    shortDesc = u"""Tsang and Hampson J. Phys. Chem. Ref. Data, 15:1087 (1986)""",
)

entry(
    index = 21,
    label = "H2O + O <=> H + HO2",
    kinetics = Arrhenius(A=(2.2e+08, 'cm^3/(mol*s)'), n=2, Ea=(61600, 'cal/mol'), T0=(1, 'K'), Tmin=(1500, 'K'),
                    Tmax=(4000, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 13""",
)

entry(
    index = 22,
    label = "H2O + OH <=> H2 + HO2",
    kinetics = Arrhenius(A=(7.9e+09, 'cm^3/(mol*s)'), n=0.43, Ea=(71700, 'cal/mol'), T0=(1, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 2, Reaction X22""",
)

entry(
    index = 23,
    label = "H2O2 <=> OH + OH",
    kinetics = Troe(
        arrheniusHigh=Arrhenius(A=(2e+12, 's^-1'), n=0.9, Ea=(48750, 'cal/mol'), T0=(1, 'K'),
                                Tmin=(500, 'K'), Tmax=(1500, 'K')),
        arrheniusLow=Arrhenius(A=(2.49e+24, 'cm^3/(mol*s)'), n=-2.3, Ea=(48750, 'cal/mol'), T0=(1, 'K'),
                                Tmin=(500, 'K'), Tmax=(1500, 'K')),
        alpha=0.42,
        T3=(1e+30, 'K'),
        T1=(1e+30, 'K'),
        efficiencies={'N#N': 1.5, 'O': 7.5, 'OO': 7.7, '[H][H]': 3.7, '[He]': 0.65, '[O][O]': 1.2, '[C-]#[O+]': 2.8,
                      'O=C=O': 1.6, }),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 6""",
)

entry(
    index = 24,
    label = "H2O2 + H <=> HO2 + H2",
    kinetics = Arrhenius(A=(5.02e+06, 'cm^3/(mol*s)'), n=2.07, Ea=(4300, 'cal/mol'), Tmin=(300, 'K'), Tmax=(2400, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 17""",
)

entry(
    index = 25,
    label = "H2O2 + H <=> H2O + OH",
    kinetics = Arrhenius(A=(2.03e+07, 'cm^3/(mol*s)'), n=2.02, Ea=(2620, 'cal/mol'), Tmin=(300, 'K'), Tmax=(2400, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 18""",
)

entry(
    index = 26,
    label = "H2O2 + O <=> HO2 + OH",
    kinetics = Arrhenius(A=(9.55e+06, 'cm^3/(mol*s)'), n=2, Ea=(3970, 'cal/mol'), Tmin=(300, 'K'), Tmax=(2500, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 19
                   Originally from Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)""",
)

entry(
    index = 27,
    label = "H2O2 + OH <=> HO2 + H2O",
    kinetics = MultiArrhenius(
        arrhenius=[Arrhenius(A=(1.74e+12, 'cm^3/(mol*s)'), n=0, Ea=(318, 'cal/mol'), Tmin=(280, 'K'), Tmax=(1640, 'K')),
                   Arrhenius(A=(7.59e+13, 'cm^3/(mol*s)'), n=0, Ea=(7269, 'cal/mol'), T0=(1, 'K'))]),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 20
                   Originally from Hong et al., J. Phys. Chem. A, 114:5718 (2010)""",
)

entry(
    index = 28,
    label = "O + H2 <=> OH + H",
    kinetics = Arrhenius(A=(50800, 'cm^3/(mol*s)'), n=2.67, Ea=(6292, 'cal/mol'), Tmin=(297, 'K'), Tmax=(2495, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 7""",
)

entry(
    index = 29,
    label = "H2 + OH <=> H2O + H",
    kinetics = Arrhenius(A=(2.14e+08, 'cm^3/(mol*s)'), n=1.52, Ea=(3450, 'cal/mol'), Tmin=(300, 'K'), Tmax=(2500, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 9
                   Originally based on Michael and Sutherland, J. Phys. Chem. 92:3853 (1988)""",
)

entry(
    index = 30,
    label = "HO2 + O <=> OH + O2",
    kinetics = Arrhenius(A=(2.85e+10, 'cm^3/(mol*s)'), n=1, Ea=(-723.9, 'cal/mol'), Tmin=(150, 'K'), Tmax=(1600, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 11
                   Originally taken from Fernandez-Ramos and Varandas, J. Phys. Chem. A 106:4077-4083 (2002)""",
)

entry(
    index = 31,
    label = "H + HO2 <=> OH + OH",
    kinetics = Arrhenius(A=(7.079e+13, 'cm^3/(mol*s)'), n=0, Ea=(295, 'cal/mol'), Tmin=(300, 'K'), Tmax=(1000, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 12
                   Originally taken by Mueller et al., Int. J. Chem. Kinetic. 31:113 (1999)""",
)

entry(
    index = 32,
    label = "H2 + O2 <=> H + HO2",
    kinetics = Arrhenius(A=(740000, 'cm^3/(mol*s)'), n=2.43, Ea=(53500, 'cal/mol'), Tmin=(400, 'K'), Tmax=(2300, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 14""",
)

entry(
    index = 33,
    label = "HO2 + HO2 <=> H2O2 + O2",
    duplicate = True,
    kinetics = MultiArrhenius(
        arrhenius=[Arrhenius(A=(1.03e+14, 'cm^3/(mol*s)'), n=0, Ea=(11040, 'cal/mol'), T0=(1, 'K'),
                                Tmin=(300, 'K'), Tmax=(1250, 'K')),
                   Arrhenius(A=(1.94e+11, 'cm^3/(mol*s)'), n=0, Ea=(-1409, 'cal/mol'), T0=(1, 'K'),
                                Tmin=(300, 'K'), Tmax=(1250, 'K'))]),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 16.""",
)

entry(
   index = 34,
   label = "HO2 + HO2 <=> H2O2 + O2",
   duplicate = True,
   kinetics = ThirdBody(
       arrheniusLow = Arrhenius(A=(6.84e+14, 'cm^6/(mol^2*s)'), n=0, Ea=(-1950, 'cal/mol'), T0=(1, 'K'))),
   shortDesc = u"""[Konnov2015]""",
   longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 2, Reaction X6""",
)

entry(
    index = 35,
    label = "HO2 + HO2 <=> H2O + O3",
    kinetics = Arrhenius(A=(100, 'cm^3/(mol*s)'), n=0, Ea=(0, 'cal/mol'), T0=(1, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 2, Reaction X4""",
)

entry(
    index = 36,
    label = "O2 + O <=> O3",
    kinetics = ThirdBody(
        arrheniusLow=Arrhenius(A=(6.53e+17, 'cm^6/(mol^2*s)'), n=-1.5, Ea=(0, 'cal/mol'), T0=(1, 'K'),
                               Tmin=(100, 'K'), Tmax=(1000, 'K')),
        efficiencies={'[Ar]': 0.0, '[He]': 0.0, '[O-][O+]=O': 2.5, '[O]': 4.0, '[O][O]': 0.95}),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 21b""",
)

entry(
    index = 37,
    label = "O2 + O + Ar <=> O3 + Ar",
    kinetics = MultiArrhenius(
        arrhenius=[Arrhenius(A=(4.29e+17, 'cm^6/(mol^2*s)'), n=-1.5, Ea=(0, 'cal/mol'), T0=(1, 'K'),
                               Tmin=(80, 'K'), Tmax=(1500, 'K')),
                   Arrhenius(A=(5.1e+21, 'cm^6/(mol^2*s)'), n=-3.2, Ea=(0, 'cal/mol'), T0=(1, 'K'),
                               Tmin=(80, 'K'), Tmax=(1500, 'K'))]),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 21a""",
)

entry(
    index = 38,
    label = "O2 + O + He <=> O3 + He",
    kinetics = MultiArrhenius(
        arrhenius=[Arrhenius(A=(4.29e+17, 'cm^6/(mol^2*s)'), n=-1.5, Ea=(0, 'cal/mol'), T0=(1, 'K'),
                               Tmin=(80, 'K'), Tmax=(1500, 'K')),
                   Arrhenius(A=(5.1e+21, 'cm^6/(mol^2*s)'), n=-3.2, Ea=(0, 'cal/mol'), T0=(1, 'K'),
                               Tmin=(80, 'K'), Tmax=(1500, 'K'))]),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Duplicated reaction of Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, 
               Reaction 21a using He as a collider instead of Ar since it is expected to behave similarly as Ar in terms
               of energy transfer.""",
)

entry(
    index = 39,
    label = "O3 + O <=> O2 + O2",
    kinetics = Arrhenius( A=(4.82e+12, 'cm^3/(mol*s)'), n=0, Ea=(4094, 'cal/mol'), T0=(1, 'K'),
                               Tmin=(200, 'K'), Tmax=(400, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 22a""",
)

entry(
    index = 40,
    label = "O3 + H <=> OH + O2",
    kinetics = Arrhenius(A=(8.43e+13, 'cm^3/(mol*s)'), n=0, Ea=(934, 'cal/mol'), T0=(1, 'K'),
                               Tmin=(200, 'K'), Tmax=(430, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 36""",
)

entry(
   index = 41,
   label = "O3 + H <=> O + HO2 ",
   kinetics = Arrhenius(A=(100, 'cm^3/(mol*s)'), n=0, Ea=(0, 'cal/mol'), T0=(1, 'K')),
   shortDesc = u"""[Konnov2015]""",
   longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 2, Reaction X15 
                  Data wasn't available from konnov 2015.""",
)

entry(
    index = 42,
    label = "O3 + OH <=> HO2 + O2",
    kinetics = Arrhenius(A=(1e+12, 'cm^3/(mol*s)'), n=0, Ea=(1870, 'cal/mol'), T0=(1, 'K'),
                               Tmin=(220, 'K'), Tmax=(450, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 37""",
)
entry(
    index = 43,
    label = "O3 + HO2 <=> OH + O2 + O2",
    kinetics = Arrhenius(A=(5.85e-4, 'cm^3/(mol*s)'), n=4.57, Ea=(-1377, 'cal/mol'), T0=(1, 'K'),
                               Tmin=(250, 'K'), Tmax=(340, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 1, Reaction 38""",
)

entry(
    index = 44,
    label = "O3 + H2 <=> OH + HO2",
    kinetics = Arrhenius(A=(6e+10, 'cm^3/(mol*s)'), n=0, Ea=(20000, 'cal/mol'), T0=(1, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 2, Reaction X18""",
)

entry(
    index = 45,
    label = "H2 + O2 <=> OH + OH",
    kinetics = Arrhenius(A=(2.04e+12, 'cm^3/(mol*s)'), n=0.44, Ea=(69155, 'cal/mol'), T0=(1, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 2, Reaction X1""",
)

entry(
    index = 46,
    label = "H2 + O2 <=> O + H2O",
    kinetics = Arrhenius(A=(3e+13, 'cm^3/(mol*s)'), n=0, Ea=(69545, 'cal/mol'), T0=(1, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 2, Reaction X2""",
)

entry(
    index = 47,
    label = "H2 + O2 + O2 <=> HO2 + HO2",
    kinetics = Arrhenius(A=(2e+17, 'cm^6/(mol^2*s)'), n=0, Ea=(25830, 'cal/mol'), T0=(1, 'K')),
    shortDesc = u"""[Konnov2015]""",
    longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 2, Reaction X3""",
)

entry(
   index = 48,
   label = "O + OH <=> HO2",
   kinetics = ThirdBody(
        arrheniusLow=Arrhenius(A=(1e+15, 'cm^6/(mol^2*s)'), n=0, Ea=(0, 'cal/mol'), T0=(1, 'K'))),
   shortDesc = u"""[Konnov2015]""",
   longDesc = u"""Konnov (2015) https://doi.org/10.1016/j.combustflame.2015.07.014, Table 2, Reaction X13""",
)

entry(
    index = 49,
    label = "HO2 + H <=> H2O2",
    kinetics = ThirdBody(
        arrheniusLow = Arrhenius(A=(6.0E+14, 'cm^6/(mol^2*s)'), n=1.25, Ea=(-270, 'cal/mol'), T0 = (1, 'K'))),
    shortDesc = u"""Mousavipour et al., Bull. Chem. Soc. Jpn., 80:1901 (2007)""",
    longDesc = u"""Taken BurkeH2O2 library Reaction X2 in Burke at el. (Table III), p. 1909 in Mousavipour et al. 
                   Declared 'negligible' by Burke at el. We want to teach RMG that this reaction matters.""",
)

entry(
    index = 50,
    label = "H2O2 + O <=> H2O + O2",
    kinetics = Arrhenius(A=(8.43E+11, 'cm^3/(mol*s)'), n=0.00, Ea=(3.970E+03, 'cal/mol'), T0=(1, 'K')),
    shortDesc = u"""Baulch et al., J. Phys. Chem. Ref. Data, 34:757 (2005)""",
    longDesc = u"""Added from the BurkeH2O2 library Reaction X5 in Burke at el. (Table III), Upper limit""",
)
