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2306.11296
ChatGPT Chemistry Assistant for Text Mining and Prediction of MOF Synthesis
[ "Zheng Zhiling ", "Zhang Oufan ", "Borgs Christian ", "Chayes Jennifer T. ", "Yaghi Omar M. " ]
We use prompt engineering to guide ChatGPT in the automation of text mining of metal-organic frameworks (MOFs) synthesis conditions from diverse formats and styles of the scientific literature. This effectively mitigates ChatGPT's tendency to hallucinate information -- an issue that previously made the use of Large L...
10.1021/jacs.3c05819
2023
2023-10-04 00:00:00
Chemicals
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2306.11296v2
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# **ChatGPT Chemistry Assistant for Text Mining and Prediction of MOF Synthesis** Zhiling Zheng,†,‡,§ Oufan Zhang, † Christian Borgs,§,◊ Jennifer T. Chayes, §,◊,††,‡‡,§§ Omar M. Yaghi†,‡,§,∥,\* † Department of Chemistry, University of California, Berkeley, California 94720, United States ‡ Kavli Energy Nanoscience I...
arxiv
other
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false
2307.01611
Intermittent in-situ high-resolution X-ray microscopy of 400-nm porous glass under uniaxial compression: study of pore changes and crack formation
[ "Schäfer Sebastian ", "Willot François ", "Rad Mansoureh Norouzi ", "Kelly Stephen T. ", "Enke Dirk ", "Silva Juliana Martins de Souza e " ]
The properties of porous glasses and their field of application strongly depend on the characteristics of the void space. Understanding the relationship between their porous structure and failure behaviour can contribute to the development of porous glasses with long-term reliability optimized for specific applicatio...
null
2023
2023-07-06 00:00:00
Ceramics
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2307.01611v1
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# Intermittent in-situ high-resolution X-ray microscopy of 400-nm porous glass under uniaxial compression: study of pore changes and crack formation Sebastian Schäfer<sup>1</sup> , François Willot,<sup>2</sup> Mansoureh Norouzi Rad,<sup>3</sup> Stephen T. Kelly,<sup>3</sup> Dirk Enke,<sup>4</sup> Juliana Martins de So...
arxiv
other
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true
true
false
2307.06477
Surface-Confined Two-Dimensional Crystal Growth on a Monolayer
[ "Jia Yanyu ", "Yuan Fang ", "Cheng Guangming ", "Tang Yue ", "Yu Guo ", "Song Tiancheng ", "Wang Pengjie ", "Singha Ratnadwip ", "Uzan Ayelet July ", "Onyszczak Michael ", "Watanabe Kenji ", "Taniguchi Takashi ", "Yao Nan ", "Schoop Leslie M ", "Wu Sanfeng " ]
Conventional vapor deposition or epitaxial growth of two-dimensional (2D) materials and heterostructures is conducted in a large chamber in which masses transport from the source to the substrate. Here we report a chamber-free, on-chip approach for growing a 2D crystalline structures directly in a nanoscale surface-c...
10.1038/s44160-023-00442-z
2023
2024-01-23 00:00:00
Nanomaterials
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2307.06477v1
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#### **Surface-Confined Two-Dimensional Crystal Growth on a Monolayer** Yanyu Jia1\*,#, Fang Yuan2,#, Guangming Cheng3 , Yue Tang1 , Guo Yu1,4 , Tiancheng Song1 , Pengjie Wang1 , Ratnadwip Singha<sup>2</sup> , Ayelet July Uzan<sup>1</sup> , Michael Onyszczak<sup>1</sup> , Kenji Watanabe<sup>5</sup> , Takashi Taniguchi...
arxiv
other
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true
true
false
2307.10759
High-density single-atom electrocatalytic centers on two-dimensional topological platinum tellurides with Te-vacancy superstructure
[ "Xu Xin ", "Wang Xuechun ", "Yu Shuming ", "Wang Chenhui ", "Liu Guowei ", "Li Hao ", "Yang Jiangang ", "Li Jing ", "Sun Tao ", "Hai Xiao ", "Li Lei ", "Liu Xue ", "Zhang Ying ", "Zhang Weifeng ", "Zhang Quan ", "Wang Kedong ", "Xu Nan ", "Ma Yaping ", "Ming Fangfei ", "Cui Pin...
Chemical activation of the intrinsically inert basal planes of transition metal dichalcogenides (TMDs) is crucial for developing high-efficiency electrocatalysts for energy technology applications. Here we report the discovery of an efficient TMD-based topological catalyst for hydrogen evolution reaction (HER), conta...
null
2023
2024-06-21 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2307.10759v3
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# **Two-dimensional topological platinum telluride superstructures with periodic tellurium** ## **vacancies** *Xin Xu1,2,3†, Xuechun Wang<sup>4</sup> †, Shuming Yu<sup>5</sup> †, Chenhui Wang3,2, Guowei Liu<sup>6</sup> , Hao Li<sup>2</sup> , Jiangang Yang<sup>2</sup> , Jing Li<sup>7</sup> , Tao Sun<sup>8</sup> , Xiao...
arxiv
other
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true
true
false
2307.12783
Ni-O-Ag catalyst enables 103-m$^2$ artificial photosynthesis with >16% solar-to-chemical energy conversion efficiency
[ "Li Yaguang ", "Meng Fanqi ", "Wu Qixuan ", "Yuan Dachao ", "Wang Haixiao ", "Liu Bang ", "Wang Junwei ", "San Xingyuan ", "Gu Lin ", "Wang Shufang ", "Meng Qingbo " ]
Herein, NiO nanosheets supported with Ag single atoms are synthesized for photothermal CO2 hydrogenation to achieve 1065 mmol g$^{-1}$ h$^{-1}$ of CO production rate under 1 sun irradiation, revealing the unparalleled weak sunlight driven reverse water-gas shift reaction (RWGS) activity. This performance is attribute...
null
2023
2023-07-27 00:00:00
Nanomaterials
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2307.12783v1
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# **Ni-O-Ag catalyst enables 103-m<sup>2</sup> artificial photosynthesis with >16%** ## **solar-to-chemical energy conversion efficiency** Yaguang Li1, 4, \*, Fanqi Meng2, 4, Qixuan Wu1, 4, Dachao Yuan3, 4 , Haixiao Wang<sup>1</sup> , Bang Liu<sup>1</sup> , Junwei Wang<sup>1</sup> , Xingyuan San<sup>1</sup> , Lin Gu<...
arxiv
other
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true
true
true
2307.14819
High-temperature superconductivity with zero-resistance and strange metal behavior in La$_{3}$Ni$_{2}$O$_{7-\delta}$
[ "Zhang Yanan ", "Su Dajun ", "Huang Yanen ", "Shan Zhaoyang ", "Sun Hualei ", "Huo Mengwu ", "Ye Kaixin ", "Zhang Jiawen ", "Yang Zihan ", "Xu Yongkang ", "Su Yi ", "Li Rui ", "Smidman Michael ", "Wang Meng ", "Jiao Lin ", "Yuan Huiqiu " ]
Recently signatures of superconductivity were observed close to 80 K in \LN\ under pressure. This discovery positions \LN\ as the first bulk nickelate with high-temperature superconductivity, but the lack of zero resistance presents a significant drawback for validating the findings. Here we report pressure measureme...
10.1038/s41567-024-02515-y
2023
2024-10-14 00:00:00
Superconductors
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2307.14819v2
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## High-temperature superconductivity with zero-resistance and strange metal behaviour in La3Ni2O7−<sup>δ</sup> Yanan Zhang,1, [∗](#page-1-0) Dajun Su,1, [∗](#page-1-0) Yanen Huang,<sup>1</sup> Zhaoyang Shan,<sup>1</sup> Hualei Sun,<sup>2</sup> Mengwu Huo,<sup>3</sup> Kaixin Ye,<sup>1</sup> Jiawen Zhang,<sup>1</sup> ...
arxiv
other
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true
2308.06537
Determining the Fundamental Failure Modes in Ni-rich Lithium Ion Battery Cathodes
[ "Wang Siyang ", "Shen Zonghao ", "Omirkhan Aigerim ", "Gavalda-Diaz Oriol ", "Ryan Mary P. ", "Giuliani Finn " ]
Challenges associated with in-service mechanical degradation of Li-ion battery cathodes has prompted a transition from polycrystalline to single crystal cathode materials. Whilst for single crystal materials, dislocation-assisted crack formation is assumed to be the dominating failure mechanism throughout battery lif...
null
2023
2023-08-15 00:00:00
Ceramics
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2308.06537v1
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# **Determining the Fundamental Failure Modes in Ni-rich Lithium Ion Battery Cathodes** Siyang Wang1,\* , Zonghao Shen1,2,3,† , Aigerim Omirkhan1,2 , Oriol Gavalda-Diaz4,1 , Mary P. Ryan1,2 , Finn Giuliani<sup>1</sup> <sup>1</sup> Department of Materials, Royal School of Mines, Imperial College London, London, SW7 2A...
arxiv
other
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2308.12657
The effect of different In$_2$O$_3$(111) surface terminations on CO$_2$ adsorption
[ "Gericke Sabrina M. ", "Kauppinen Minttu M. ", "Wagner Margareta ", "Riva Michele ", "Franceschi Giada ", "Posada-Borbón Alvaro ", "Rämisch Lisa ", "Pfaff Sebastian ", "Rheinfrank Erik ", "Imre Alexander M. ", "Preobrajenski Alexei B. ", "Appelfeller Stephan ", "Blomberg Sara ", "Merte Lin...
In$_2$O$_3$-based catalysts have shown high activity and selectivity for CO$_2$ hydrogenation to methanol, however the origin of the high performance of In$_2$O$_3$ is still unclear. To elucidate the initial steps of CO$_2$ hydrogenation over In$_2$O$_3$, we have combined X-ray Photoelectron Spectroscopy (XPS) and De...
10.1021/acsami.3c07166
2023
2023-08-25 00:00:00
Semiconductors
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2308.12657v1
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# The effect of different In2O3(111) surface terminations on CO<sup>2</sup> adsorption Sabrina M. Gericke,∗,†,@ Minttu M. Kauppinen,∗,‡,@ Margareta Wagner,¶ Michele Riva,¶ Giada Franceschi,¶ Alvaro Posada-Borb´on,‡ Lisa R¨amisch,† Sebastian Pfaff,† Erik Rheinfrank,¶ Alexander M. Imre,¶ Alexei B. Preobrajenski,§ Ste...
arxiv
other
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true
2308.14403
Dense and single-phase KTaO$_{3}$ ceramics obtained by spark plasma sintering
[ "Féger L. 2 and 3", "Giovannelli F. 2 and 3", "Vats G. 2 and 3", "Alves J. ", "Pignon B. ", "Salje E. K. H. ", "Monot-Laffez I. ", "Nataf G. F. " ]
Potassium tantalate (KTaO$_{3}$) is a promising material for dielectric applications at low temperature. However, dense and single-phase ceramics cannot be obtained by conventional sintering because of the evaporation of potassium that leads to secondary phases. Here, we demonstrate that spark plasma sintering is a s...
10.1016/j.jeurceramsoc.2023.07.060
2023
2023-10-23 00:00:00
Ceramics
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2308.14403v1
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# Dense and single-phase KTaO<sup>3</sup> ceramics obtained by spark plasma sintering L. Féger1, <sup>±</sup> , F. Giovannelli<sup>1</sup> , G. Vats2,3 , J. Alves<sup>1</sup> , B. Pignon<sup>1</sup> , E. K. H. Salje<sup>4</sup> , I. Monot-Laffez 1 , G. F. Nataf1,\* > ± [lucile.feger@univ-tours.fr](mailto:lucile.feger...
arxiv
other
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true
2309.13131
Impact of Co2C Nanoparticles on Enhancing the Critical Current Density of Bi-2223 Superconductor
[ "Ali Md. Arif ", "Karan Sourav M ", "Roy Nirmal ", "Banerjee S. S. " ]
We have investigated the superconducting properties of nanocomposite pellets made from Bi-2223 and Co2C powders. There is loss of superconducting fraction in the nanocomposites, but the retained superconducting fraction exhibits robust bulk superconducting properties, having Tc ~ 109 K which was found to be comparabl...
null
2023
2024-02-08 00:00:00
Nanomaterials
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2309.13131v2
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# **Impact of Co2C Nanoparticles on Enhancing the Critical Current Density of Bi-2223 Superconductor** Md. Arif Ali<sup>1</sup> , Sourav M Karan<sup>1</sup> , Nirmal Roy<sup>1</sup> , S. S. Banerjee1,\* *<sup>1</sup>Department of Physics, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh 208016, India* ##...
arxiv
other
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true
2309.14377
Quantifying Li-content for compositional tailoring of lithium ferrite ceramics
[ "Granados-Miralles C. ", "Serrano A. ", "Prieto P. ", "Guzmán-Mínguez J. ", "Prieto J. E. ", "Friedel A. M. ", "García-Martín E. ", "Fernández J. F. ", "Quesada A. " ]
Owing to their multiple applications, lithium ferrites are relevant materials for several emerging technologies. For instance, LiFeO2 has been spotted as an alternative cathode material in Li-ion batteries, while LiFe5O8 is the lowest damping ferrite, holding promise in the field of spintronics. The Li-content in lit...
10.1016/j.jeurceramsoc.2023.02.011
2023
2023-09-27 00:00:00
Ceramics
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2309.14377v1
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Contents lists available at [ScienceDirect](www.sciencedirect.com/science/journal/09552219) ![](_page_0_Picture_2.jpeg) Journal of the European Ceramic Society journal homepage: [www.elsevier.com/locate/jeurceramsoc](https://www.elsevier.com/locate/jeurceramsoc) # Quantifying Li-content for compositional tailoring...
arxiv
other
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false
2310.05974
Photocatalytic active ZnO$_{1-x}$S$_x$@CNTs heteronanostructures
[ "Bjelajac Andjelika LPICM, LIST", "Florea Ileana LPICM", "Zamfir Mihai LPICM", "Nenez Sandrine Tusseau LPMC, CNRS, Ecole Polytechnique, IPP", "Cojocaru Costel Sorin LPICM" ]
Herein, we report on the use of vertically aligned multiwall carbon nanotubes (CNTs) films as support for ZnO/ZnS photocatalytic active nanostructures. The CNTs were synthetized via a hot-filament chemical vapor deposition (HfCVD), using Fe catalyst on top of Al$_2$O$_3$ buffer layer. Controlled point defects in the ...
10.1088/1361-6528/acf6c8
2023
2023-10-11 00:00:00
Nanomaterials
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2310.05974v1
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# **Photocatalytic active ZnO1-xSx@CNTs heteronanostructures** Andjelika Bjelajaca, b\*, Ileana Floreaa, c, Mihai Zamfira, d, Sandrine Tusseau Neneze and Costel Sorin Cojocarua a LPICM, CNRS, Ecole polytechnique, IP Paris, 91228 Palaiseau Cedex, France. b Luxembourg Institute of Science and Technology (LIST), Maison...
arxiv
other
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false
2310.10253
In-Situ Single Particle Reconstruction Reveals 3D Evolution of PtNi Nanocatalysts During Heating
[ "Wang Yi-Chi ", "Slater Thomas J A ", "Leteba Gerard M. ", "Lang Candace I ", "Wang Zhong Lin ", "Haigh Sarah J " ]
Tailoring nanoparticles composition and morphology is of particular interest for improving their performance for catalysis. A challenge of this approach is that the nanoparticles optimized initial structure often changes during use. Visualizing the three dimensional (3D) structural transformation in situ is therefore...
null
2023
2023-10-17 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2310.10253v1
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# In-Situ Single Particle Reconstruction Reveals 3D Evolution of PtNi Nanocatalysts During Heating *Yi-Chi Wang1,2,3, Thomas J. A. Slater<sup>4</sup> \*, Gerard M. Leteba<sup>5</sup> , Candace I. Lang<sup>5</sup> , Zhong Lin Wang1,6, Sarah J. Haigh<sup>2</sup> \** 1. Beijing Institute of Nanoenergy and Nanosystems, ...
arxiv
other
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true
true
2310.13351
Elasto-plastic residual stress analysis of selective laser sintered porous materials based on 3D-multilayer thermo-structural phase-field simulations
[ "Yang Yangyiwei ", "Bharech Somnath ", "Finger Nick ", "Zhou Xiandong ", "Schroeder Joerg ", "Xu Bai-Xiang " ]
Residual stress and plastic strain in additive manufactured materials can exhibit significant microscopic variation at the powder scale, profoundly influencing the overall properties of printed components. This variation depends on processing parameters and stems from multiple factors, including differences in powder...
10.1038/s41524-024-01296-5
2023
2024-06-19 00:00:00
Metals
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2310.13351v2
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# Elasto-plastic residual stress analysis of selective laser sintered porous materials based on 3D-multilayer thermo-structural phase-field simulations Yangyiwei Yang<sup>1</sup> , Somnath Bharech<sup>1</sup> , Nick Finger<sup>1</sup> , Xiandong Zhou2,\*, Jorg Schr ¨ oder ¨ 3 , and Bai-Xiang Xu1,\* 1Mechanics of Func...
arxiv
other
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true
false
2311.00195
Effect of annealing in eutectic high-entropy alloy superconductor NbScTiZr
[ "Seki Takeru ", "Arima Hiroto ", "Kawasaki Yuta ", "Nishizaki Terukazu ", "Mizuguchi Yoshikazu ", "Kitagawa Jiro " ]
We investigated the impact of annealing on the structural characteristics and superconducting critical temperature ($T_\mathrm{c}$) of the eutectic high-entropy alloy (HEA) superconductor NbScTiZr. The HEA manifests an eutectic microstructure composed of body-centered cubic (bcc) and hexagonal close-packed phases. Bo...
null
2023
2023-11-02 00:00:00
Superconductors
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2311.00195v1
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# Effect of annealing in eutectic high-entropy alloy superconductor NbScTiZr Takeru Seki<sup>1</sup> , Hiroto Arima<sup>2</sup> , Yuta Kawasaki<sup>3</sup> , Terukazu Nishizaki<sup>3</sup> , Yoshikazu Mizuguchi<sup>2</sup> , Jiro Kitagawa1\* <sup>1</sup>Department of Electrical Engineering, Faculty of Engineering, Fu...
arxiv
other
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true
true
true
2311.10839
Conformal TiO$_2$ aerogel-like films by plasma deposition: from omniphobic antireflective coatings to perovskite solar cells photoelectrodes
[ "Obrero Jose M. Ken", "Contreras-Bernal Lidia Ken", "Aparicio Francisco J. Ken", "Rojas Teresa C. Ken", "Ferrer Francisco J. Ken", "Orozco Noe Ken", "Saghi Zineb Ken", "Czermak Triana Ken", "Pedrosa Jose M. Ken", "Lopez-Santos Carmen Ken", "Kostya Ken", "Ostrikov ", "Borras Ana ...
The ability to control porosity in oxide thin films is one of the key factors that determine their properties. Despite the abundance of dry processes for the synthesis of oxide porous layers, the high porosity range is typically achieved by spin-coating-based wet chemical methods. Besides, special techniques such as ...
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2023
2023-11-21 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2311.10839v1
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# Conformal TiO2 aerogel-like films by plasma deposition: from omniphobic antireflective coatings to perovskite solar cells photoelectrodes Jose M. Obrero,<sup>a</sup> Lidia Contreras-Bernal,<sup>a</sup> Francisco J. Aparicio,a,b Teresa C. Rojas,<sup>a</sup> Francisco J. Ferrer,<sup>c</sup> Noe Orozco,<sup>a</sup> Zin...
arxiv
other
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false
2312.03206
Seamless monolithic three-dimensional integration of single-crystalline films by growth
[ "Kim Ki Seok ", "Seo Seunghwan ", "Kwon Junyoung ", "Lee Doyoon ", "Kim Changhyun ", "Ryu Jung-El ", "Kim Jekyung ", "Song Min-Kyu ", "Suh Jun Min ", "Jung Hang-Gyo ", "Jo Youhwan ", "Ahn Hogeun ", "Lee Sangho ", "Cho Kyeongjae ", "Jeon Jongwook ", "Seol Minsu ", "Park Jin-Hong ", ...
The demand for the three-dimensional (3D) integration of electronic components is on a steady rise. The through-silicon-via (TSV) technique emerges as the only viable method for integrating single-crystalline device components in a 3D format, despite encountering significant processing challenges. While monolithic 3D...
null
2023
2023-12-08 00:00:00
Semiconductors
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2312.03206v2
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#### **Seamless monolithic three-dimensional integration of single-crystalline films by growth** Ki Seok Kim1,4† , Seunghwan Seo1,4† , Junyoung Kwon2,3† , Doyoon Lee4,8† , Changhyun Kim2,3† , Jung-El Ryu1,4, Jekyung Kim1,4, Min-Kyu Song1,4, Jun Min Suh1,4, Hang-Gyo Jung5 , Youhwan Jo6 , Hogeun Ahn5 , Sangho Lee1,4, Ky...
arxiv
other
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true
true
2312.04376
The Er doping of ZnCr2O4
[ "Yang Chen ", "Ni Danrui ", "Yao Nan ", "Cava Robert J. " ]
Magnetic Er3+ is doped into the well-studied frustrated normal spinel ZnCr2O4. Various spectroscopies are employed to prove that Er3+ successfully enters the spinel to form ZnCr2-xErxO4 for x less than 0.005. The low levels of Er3+ doping possible nonetheless have a significant effect on the frustrated magnetism and ...
null
2023
2023-12-08 00:00:00
Ceramics
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2312.04376v1
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### **The Er doping of ZnCr2O<sup>4</sup>** Chen Yang1,2, Danrui Ni<sup>1</sup> , Nan Yao<sup>3</sup> , and Robert J. Cava1\* <sup>1</sup> Department of Chemistry, Princeton University, Princeton, New Jersey, 08544 <sup>2</sup> Department of Electrical and Computer Engineering, Princeton University, Princeton, New J...
arxiv
other
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true
2312.10280
Exploring Structural and Electronic Properties of Topological Insulator/Graphene Nano-heterostructures
[ "Gallardo Valentina ", "Arce Barbara ", "Muñoz Francisco ", "Martín Rodolfo San ", "Zubritskaya Irina ", "Giraldo-Gallo Paula ", "Manoharan Hari ", "Parra Carolina " ]
There is great interest in the study of topological insulator-based heterostructures due to expected emerging phenomena. However, a challenge of topological insulator (TI) research is the contribution of the bulk conduction to the TI surface states. Both strain engineering and thickness control routes, which have bee...
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2023
2023-12-19 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2312.10280v1
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# **Exploring Structural and Electronic Properties of Topological Insulator/Graphene Nano-heterostructures** Valentina Gallardo <sup>a</sup> , Barbara Arce <sup>a</sup> , Francisco Muñoz <sup>b</sup> , Rodolfo San Martín <sup>a</sup> , Irina Zubritskaya <sup>c</sup> , Paula Giraldo-Gallo <sup>d</sup> , Hari Manoharan ...
arxiv
other
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2402.01437
Structural and optical characterization of NiO polycrystalline thin films fabricated by spray-pyrolysis
[ "Das Lakshmi ", "Canto-Aguilar Esdras J. ", "Tapani Tlek ", "Lin Haifeng ", "Bhuvanendran Hinduja ", "Boulanger Nicolas ", "Salh Roushdey ", "Gracia-Espino Eduardo ", "Maccaferri Nicolò " ]
Nickel (II) oxide, NiO, a wide band gap Mott insulator characterized by strong Coulomb repulsion between d-electrons and displaying antiferromagnetic order at room temperature, has gained attention in recent years as a very promising candidate for applications in a broad set of areas, including chemistry and metallur...
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2024
2024-02-05 00:00:00
Magnetic
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2402.01437v1
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# **Structural and optical characterization of NiO polycrystalline thin films fabricated by spray-pyrolysis** **Lakshmi Das, Esdras J. Canto-Aguilar, Tlek Tapani, Haifeng Lin, Hinduja Bhuvanendran, Nicolas Boulanger, Roushdey Salh, Eduardo Gracia-Espino, Nicolò Maccaferri** <sup>1</sup>Department of Physics, Umeå Uni...
arxiv
other
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false
2402.05315
Relaxation processes of densified silica glass
[ "Cornet Antoine ", "Martinez Valerie ", "de Ligny Dominique ", "Champagnon Bernard ", "Martinet Christine " ]
Densified SiO2 glasses, obtained from different pressure and temperature routes have been annealed over a wide range of temperature far below the glass transition temperature (500$^\circ$C-900$^\circ$C). Hot and cold compressions were useful to separate the effects of pressure and the compression temperature. In-situ...
10.1063/1.4977036
2024
2024-02-09 00:00:00
Ceramics
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2402.05315v1
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# **Relaxation processes of densified silica glass** Antoine Cornet, 1,a) Valérie Martinez, <sup>1</sup> Dominique de Ligny, <sup>2</sup> Bernard Champagnon<sup>1</sup> and Christine Martinet<sup>1</sup> <sup>1</sup>*Univ Lyon, Université Claude Bernard Lyon 1, CNRS, Institut Lumière Matière, F-69622, VILLEURBANNE, F...
arxiv
other
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2402.09220
Textural properties of dense granular pastes produced by kneading
[ "Auxois Mathilde ", "Minière Marine ", "Bertrand-Drira Chloé ", "Salvatori Fabien ", "Verstraete Jan ", "Manneville Sébastien ", "Divoux Thibaut " ]
The efficiency of supported catalysts depends on the porous microstructure of their solid support, which regulates mass transfer, exposure to the active phase, and mechanical strength. Here, we focus on the manufacturing of a specific type of catalytic support, $\gamma$-alumina extrudates, by a kneading-extrusion pro...
10.1103/PhysRevMaterials.8.063403
2024
2024-09-17 00:00:00
Ceramics
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2402.09220v1
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# arXiv:2402.09220v1 [cond-mat.soft] 14 Feb 2024 # Textural properties of dense granular pastes produced by kneading Mathilde Auxois,1, 2 Marine Mini`ere,<sup>1</sup> Chlo´e Bertrand-Drira,<sup>1</sup> Fabien Salvatori,<sup>1</sup> Jan Verstraete,<sup>1</sup> S´ebastien Manneville,<sup>2</sup> and Thibaut Divoux<sup...
arxiv
other
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2402.11694
Influence of mechanical compliance of the substrate on the morphology of nanoporous gold thin films
[ "Shahriar Sadi ", "Somayajula Kavya ", "Winkeljohn Conner ", "Mason Jeremy ", "Seker Erkin " ]
Nanoporous gold (np-Au) has found use in applications ranging from catalysis to biosensing where pore morphology plays a critical role in performance. While morphology evolution of bulk np-Au has been widely studied, knowledge about its thin film form is limited. This work hypothesizes that mechanical compliance of t...
null
2024
2024-02-20 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by-nc-sa/4.0/
http://arxiv.org/pdf/2402.11694v1
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# Influence of mechanical compliance of the substrate on the morphology of nanoporous gold thin films Sadi Shahriar<sup>a</sup> , Kavya Somayajula<sup>b</sup> , Conner Winkeljohn<sup>a</sup> , Jeremy Mason<sup>a</sup> , Erkin Sekerc,\* *<sup>a</sup>Department of Materials Science and Engineering, University of Califo...
arxiv
other
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2402.11859
Multistep severe plastic deformation to achieve non-rare earth bulk magnets with high {\alpha}-MnBi phase content
[ "Weissitsch L. ", "Wurster S. ", "Krenn H. ", "Bachmaier A. " ]
The ferromagnetic {\alpha}-MnBi phase as non-rare earth magnetic material has gained increasing interest, but fabrication of large volumes containing a significant amount of {\alpha}-MnBi is still challenging. Targeting successful processing strategies, we apply multistep severe plastic deformation with intermediate ...
null
2024
2024-02-20 00:00:00
Magnetic
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2402.11859v1
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# **Multistep severe plastic deformation to achieve non-rare earth bulk magnets with high α-MnBi phase content** L. Weissitsch<sup>a</sup> , S. Wurster<sup>a</sup> , H. Krenn<sup>b</sup> , A. Bachmaier<sup>a</sup>\* *<sup>a</sup> Erich Schmid Institute of Materials Science, Austrian Academy of Sciences, Jahn Strasse ...
arxiv
other
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true
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2402.15305
Ubiquitous short-range order in multi-principal element alloys
[ "Han Ying ", "Chen Hangman ", "Sun Yongwen ", "Liu Jian ", "Wei Shaolou ", "Xie Bijun ", "Zhang Zhiyu ", "Zhu Yingxin ", "Li Meng ", "Yang Judith ", "Chen Wen ", "Cao Penghui ", "Yang Yang " ]
Recent research in multi-principal element alloys (MPEAs) has increasingly focused on the exploration and exploitation of short-range order (SRO) to enhance material performance. However, the understanding of SRO formation and the precise tuning of it within MPEAs remains poorly understood, limiting the comprehension...
null
2024
2024-02-26 00:00:00
Metals
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2402.15305v1
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# **Ubiquitous short-range order in multi-principal element alloys** Ying Han1,† , Hangman Chen2,† , Yongwen Sun<sup>1</sup> , Jian Liu<sup>3</sup> , Shaolou Wei4,# , Bijun Xie<sup>2</sup> , Zhiyu Zhang<sup>1</sup> , Yingxin Zhu<sup>1</sup> , Meng Li<sup>5</sup> , Judith Yang5,6 , Wen Chen<sup>3</sup> , Penghui Cao2,\...
arxiv
other
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true
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2403.06713
Influence of Li-stoichiometry on electrical and acoustic properties and temperature stability of Li(Nb,Ta)O$_{3}$ solid solutions up to 900 {\deg}C
[ "Tichy-Rács Éva Institute of Energy Research and Physical\n Technologies, University of Technology Clausthal", "Hurskyy Stepan Institute\n of Energy Research and Physical Technologies, University of Technology\n Clausthal", "Yakhnevych Uliana Institute of Energy Research and Physical\n Technologies, Univ...
The current work is focused on the impact of the lithium stoichiometry on electrical conductivity, acoustic properties and high-temperature stability of single crystalline Li(Nb,Ta)O$_{3}$ at high temperatures. The crystals grown from Li-deficient melts were treated by the vapor transport equilibration (VTE) method, ...
null
2024
2024-03-12 00:00:00
Ceramics
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2403.06713v1
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### Influence of Li-stoichiometry on electrical and acoustic properties and temperature stability of Li(Nb,Ta)O<sup>3</sup> solid solutions up to 900 °C Éva Tichy-Rács\*, Stepan Hurskyy, Uliana Yakhnevych, Piotr Gaczyński, Steffen Ganschow, Holger Fritze and Yuriy Suhak É. Tichy-Rács, S. Hurskyy, U. Yakhnevych, P. Ga...
arxiv
other
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true
true
true
2403.16455
Topological iron silicide with H* intermediate modulated surface for efficient electrocatalytic hydrogenation of nitrobenzene in neutral medium
[ "Wang Yuchen ", "Liu Yaoyu ", "Zhao Zhiyue ", "Zheng Zhikeng ", "Balu Alina M. ", "Luque Rafael ", "Yan Kai " ]
Electrocatalytic hydrogenation of nitrobenzene (Ph-NO2) reaction (EHNR) has been considered as a potential alternative to the traditional thermocatalytic process in the production of high-value aniline (Ph-NH2). However, due to the absence of robust catalyst and low surface H* coverage, the EHNR faces the challenges ...
null
2024
2024-03-26 00:00:00
Nanomaterials
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2403.16455v1
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![](_page_0_Picture_2.jpeg) # HIGHLIGHTED PAPER # Topological iron silicide with H\* intermediate modulated surface for efficient electrocatalytic hydrogenation of nitrobenzene in neutral medium Yuchen Wang 1,# , Yaoyu Liu 1,# , Zhiyue Zhao <sup>1</sup> , Zhikeng Zheng <sup>1</sup> , Alina M. Balu 2,⇑ , Rafael Luque...
arxiv
other
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false
2403.16461
Recent Advances on Transition-Metal-Based Layered Double Hydroxides Nanosheets for Electrocatalytic Energy Conversion
[ "Wang Yuchen ", "Zhang Man ", "Liu Yaoyu ", "Zheng Zhikeng ", "Liu Biying ", "Chen Meng ", "Guan Guoqing ", "Yan Kai " ]
Transition-metal-based layered double hydroxides (TM-LDHs) nanosheets are promising electrocatalysts in the renewable electrochemical energy conversion system, which are regarded as alternatives to noble metal-based materials. In this review, recent advances on effective and facile strategies to rationally design TM-...
null
2024
2024-03-26 00:00:00
Nanomaterials
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2403.16461v1
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# **Recent Advances on Transition-Metal-Based Layered Double Hydroxides Nanosheets for Electrocatalytic Energy Conversion** *Yuchen Wang,† Man Zhang,† Yaoyu Liu, Zhikeng Zheng, Biying Liu, Meng Chen, Guoqing Guan,\* Kai Yan\** Dr. Y. Wang, M. Zhang, Y. Liu, Z. Zheng, B. Liu, Prof. K. Yan Guangdong Provincial Key Labo...
arxiv
other
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true
false
2404.06896
Unravelling the Band Structure and Orbital Character of a $\pi$-Conjugated 2D Graphdiyne-Based Organometallic Network
[ "D'Agosta Paolo ", "Achilli Simona ", "Tumino Francesco ", "Biroli Alessio Orbelli ", "Di Santo Giovanni ", "Petaccia Luca ", "Onida Giovanni ", "Bassi Andrea Li ", "Lobo-Checa Jorge ", "Casari Carlo S. " ]
Graphdiyne-based carbon systems generate intriguing layered sp-sp$^2$ organometallic lattices, characterized by flexible acetylenic groups connecting planar carbon units through metal centers. At their thinnest limit, they can result in two-dimensional (2D) organometallic networks exhibiting unique quantum properties...
null
2024
2024-04-11 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2404.06896v1
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# Unravelling the Band Structure and Orbital Character of a *π*-Conjugated 2D Graphdiyne-Based Organometallic Network Paolo D'Agosta*<sup>a</sup>* , Simona Achilli*b,*<sup>∗</sup> , Francesco Tumino*a,c*, Alessio Orbelli Biroli*<sup>d</sup>* , Giovanni Di Santo*<sup>e</sup>* , Luca Petaccia*<sup>e</sup>* , Giovanni On...
arxiv
other
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true
true
false
2404.10669
Arsenic diffusion in MOVPE-Grown GaAs/Ge epitaxial structures
[ "Orejuela V. ", "Garcia-Tabares E. ", "Rey-Stolle I. ", "Garcia I. " ]
Germanium is reemerging as a prominent material in the semiconductor field, particularly for electronic applications, photonics, photovoltaics and thermophotovoltaics. Its combination with III-V compound semiconductors through epitaxial growth by metal organic vapor phase epitaxy (MOVPE) is instrumental and thus, the...
null
2024
2024-04-17 00:00:00
Semiconductors
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2404.10669v1
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# **Arsenic diffusion in MOVPE-Grown GaAs/Ge epitaxial structures** V. Orejuela\*, I. Rey-Stolle, I. García\* Universidad Politécnica de Madrid Instituto de Energía Solar Semiconductores III-V Avenida Complutense, 30 Madrid 28040, Spain \*Corresponding authors' emails: [victor.orejuela@ies.upm.es](mailto:victor.orejue...
arxiv
other
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false
2404.12822
Mixed Polyanionic NaFe$_{1.6}$V$_{0.4}$(PO$_{4}$)(SO$_{4}$)$_{2}$@CNT Cathode for Sodium-ion Batteries: Electrochemical Diffusion Kinetics and Distribution of Relaxation Time Analysis at Different Temperatures
[ "Pati Jayashree ", "Dhaka Rajendra S. " ]
We report the electrochemical sodium-ion kiinetics and distribution of relaxation time (DRT) analysis of a newly designed mixed polyanionic NaFe$_{1.6}$V$_{0.4}$(PO$_{4}$)(SO$_{4}$)$_{2}$@CNT composite as a cathode. The specific capacity of 104 mAhg$^{-1}$ is observed at 0.1~C with the average working voltage of $\si...
null
2024
2024-04-22 00:00:00
Composites
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2404.12822v1
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# Mixed Polyanionic NaFe1.6V0.4(PO4)(SO4)2@CNT Cathode for Sodium-ion Batteries: Electrochemical Diffusion Kinetics and Distribution of Relaxation Time Analysis at Different Temperatures . Jayashree Pati and Rajendra S. Dhaka[∗](#page-0-0) Department of Physics, Indian Institute of Technology Delhi, Hauz Khas, New D...
arxiv
other
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true
true
2404.14085
High efficient sunlight-driven CO2 hydrogenation to methanol over NiZn intermetallic catalysts under atmospheric pressure
[ "Han Linjia ", "Meng Fanqi ", "Bai Xianhua ", "Wu Qixuan ", "Luo Yanhong ", "Shi Jiangjian ", "Li Yaguang ", "Li Dongmei ", "Meng Qingbo " ]
The synthesis of solar methanol through direct CO2 hydrogenation using solar energy is of great importance in advancing a sustainable energy economy. In this study, non-precious NiZn intermetallic/ZnO catalyst is reported to catalyze the hydrogenation of CO2 to methanol using sunlight irradiation (1sun). The NiZn-ZnO...
null
2024
2024-04-23 00:00:00
Composites
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2404.14085v1
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# **High efficient sunlight-driven CO<sup>2</sup> hydrogenation to methanol over NiZn intermetallic catalysts under atmospheric pressure** Linjia Han1,2,† , Fanqi Meng3,† , Xianhua Bai<sup>1</sup> , Qixuan Wu<sup>4</sup> , Yanhong Luo1,2,5 \*, Jiangjian Shi<sup>1</sup> , Yaguang Li 4, \*, Dongmei Li1,2,5 , Qingbo Meng...
arxiv
other
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true
true
true
2404.17965
Influence of chemical substitution and sintering temperature on the structural, magnetic and magnetocaloric properties of La1-xSrxMn1-yFeyO3
[ "Brahiti N. ", "Balli M. ", "Eskandari M. Abbasi ", "Boukili A. El ", "Fournier P. " ]
The effects of sintering temperature (Ts) and chemical substitution on the structural and magnetic properties of manganite compounds La1-xSrxMn1-yFeyO3 (0.025 <= x <= 0.7; y= 0.01,0.15) are explored in a search to optimize their magnetocaloric properties around room temperature. A ferromagnetic (FM) to paramagnetic (...
null
2024
2024-04-30 00:00:00
Ceramics
http://creativecommons.org/publicdomain/zero/1.0/
http://arxiv.org/pdf/2404.17965v1
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# Influence of chemical substitution and sintering temperature on the structural, magnetic and magnetocaloric properties of ିି N. Brahiti <sup>1</sup> , M. Balli<sup>2</sup>, M. Abbasi Eskandari <sup>1</sup> , A. El Boukili3,4, P. Fournier <sup>1</sup> 1 Institut quantique, Regroupement québécois sur les matériaux de...
arxiv
other
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true
true
2405.10464
Epitaxially Grown Single-Crystalline SrTiO3 Membranes Using a Solution-Processed, Amorphous SrCa2Al2O6 Sacrificial Layer
[ "Varshney Shivasheesh ", "Ramis Martí ", "Choo Sooho ", "Coll Mariona ", "Jalan Bharat " ]
Water-soluble sacrificial layers based on epitaxially-grown, single crystalline (Ca, Sr, Ba)3Al2O6 layer are widely used for creating free-standing perovskite oxide membranes. However, obtaining these sacrificial layers with intricate stoichiometry remains a challenge, especially for molecular beam epitaxy (MBE). In ...
null
2024
2024-05-20 00:00:00
Ceramics
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2405.10464v1
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# **Epitaxially Grown Single-Crystalline SrTiO3 Membranes Using a Solution-Processed, Amorphous SrCa2Al2O6 Sacrificial Layer** Shivasheesh Varshney1 , Martí Ramis2 , Sooho Choo1 , Mariona Coll2 , Bharat Jalan1 1 Department of Chemical Engineering and Materials Science, University of Minnesota, Twin Cities, Minnesota,...
arxiv
other
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false
2406.06752
Direct observation of phase change accommodating hydrogen uptake in bimetallic nanoparticles
[ "Matte Lívia P. ", "Jaugstetter Maximilian ", "Thill Alisson S. ", "Mishra Tara P. ", "Escudero Carlos ", "Conti Giuseppina ", "Poletto Fernanda ", "Nemsak Slavomir ", "Bernardi Fabiano " ]
Hydrogen holds great promise as a cleaner alternative to fossil fuels, but its efficient and affordable storage remains a significant challenge. Bimetallic systems, such as Pd-Ni, present a promising option for storing hydrogen. In this study, using the combination of different cuttingedge X-ray and electron techniqu...
null
2024
2025-03-05 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2406.06752v2
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# Direct observation of phase change accommodating hydrogen uptake in bimetallic nanoparticles Lívia P. Matte,1,2 Maximilian Jaugstetter,<sup>3</sup> Alisson S. Thill,<sup>1</sup>Tara P. Mishra,<sup>4</sup> Carlos Escudero,<sup>5</sup> Giuseppina Conti,2,6 Fernanda Poletto,<sup>7</sup> Slavomir Nemsak,2,6\* Fabiano Be...
arxiv
other
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null
true
true
false
2406.15521
Impact of surface treatments on the electron affinity of nitrogen-doped ultrananocrystalline diamond
[ "Chambers Andre ", "McCloskey Daniel J. ", "Dontschuk Nikolai ", "Hashem Hassan N. Al ", "Murdoch Billy J. ", "Stacey Alastair ", "Prawer Steven ", "Ahnood Arman " ]
In recent years, various forms of nanocrystalline diamond (NCD) have emerged as an attractive group of diamond/graphite mixed-phase materials for a range of applications from electron emission sources to electrodes for neural interfacing. To tailor their properties for different uses, NCD surfaces can be terminated w...
10.1016/j.apsusc.2024.159710
2024
2024-06-25 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by-sa/4.0/
http://arxiv.org/pdf/2406.15521v1
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# Impact of surface treatments on the electron affinity of nitrogendoped ultrananocrystalline diamond Andre Chambers,[1](#page-0-0),2\* Daniel J. McCloskey,2 Nikolai Dontschuk,2 Hassan N. Al Hashem,3 Billy J. Murdoch,4 Alastair Stacey,2,5 and Steven Prawer,2 and Arman Ahnood2,3 1 Department of Mechanical Engineering,...
arxiv
other
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true
true
false
2407.01390
Rapid synthesis of uniformly small nickel nanoparticles for the surface functionalization of epitaxial graphene
[ "Vlamidis Ylea ", "Forti Stiven ", "Rossi Antonio ", "Marinelli Carmela ", "Coletti Camilla ", "Heun Stefan ", "Veronesi Stefano " ]
Nickel nanoparticles (Ni NPs), thanks to their peculiar properties, are interesting materials for many applications including catalysis, hydrogen storage, and sensors. In this work, Ni NPs are synthesized in aqueous solution by a simple and rapid procedure with cetyltrimethylammonium bromide (CTAB) as a capping agent...
10.1002/ppsc.202400141
2024
2024-10-23 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2407.01390v1
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# **Rapid synthesis of uniformly small nickel nanoparticles for the surface functionalization of epitaxial graphene** *Ylea Vlamidis\* , Stiven Forti, Antonio Rossi, Carmela Marinelli, Camilla Coletti, Stefan Heun, Stefano Veronesi\** Y. Vlamidis, S. Heun, S. Veronesi NEST, Istituto Nanoscienze–CNR and Scuola Normale...
arxiv
other
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true
false
2407.02600
Macroscopic uniform 2D moir\'e superlattices with controllable angles
[ "Zaborski Gregory Jr.", "Majchrzak Paulina E. ", "Lai Samuel ", "Johnson Amalya C. ", "Saunders Ashley P. ", "Zhu Ziyan ", "Deng Yujun ", "Lu Donghui ", "Hashimoto Makoto ", "Shen Z-X ", "Liu Fang " ]
Moir\'e superlattices, engineered through precise stacking of van der Waals (vdW) layers, hold immense promise for exploring strongly correlated and topological phenomena. However, these applications have been held back by the common preparation method: tear-and-stack of Scotch tape exfoliated monolayers. It has low ...
null
2024
2024-07-04 00:00:00
Semiconductors
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2407.02600v1
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# **Macroscopic uniform 2D moiré superlattices with controllable angles** Gregory Zaborski Jr.<sup>1</sup> , Paulina E. Majchrzak<sup>2</sup> , Samuel Lai<sup>1</sup> , Amalya C. Johnson<sup>1</sup> , Ashley P. Saunders<sup>3</sup> , Ziyan Zhu<sup>4</sup> , Yujun Deng4,5, Donghui Lu4,5 , Makoto Hashimoto4,5 , Z-X Shen...
arxiv
other
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true
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false
2407.11580
Extension of a phase-field KKS model to predict the microstructure evolution in LPBF AlSi10Mg alloy submitted to non isothermal processes
[ "Fetni Seifallah ", "Delahaye Jocelyn ", "Sepúlveda Héctor ", "Duchêne Laurent ", "Habraken Anne Marie ", "Mertens Anne " ]
The out-of-equilibrium heterogeneous microstructure typical of AlSi10Mg processed by Laser Powder Bed Fusion (LPBF) is often modified by further heat treatment to improve its ductility. According to literature, extensive experimental investigations are generally required in order to optimize these heat treatments. In...
10.1016/j.commatsci.2024.113197
2024
2024-07-17 00:00:00
Metals
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2407.11580v1
null
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# <span id="page-0-0"></span>Extension of a phase-field KKS model to predict the microstructure evolution in LPBF AlSi10Mg alloy submitted to non isothermal processes Seifallah Fetni<sup>a</sup> , Jocelyn Delahaye<sup>b</sup> , H´ector Sep´ulveda<sup>a</sup> , Laurent Duchˆene<sup>a</sup> , Anne Marie Habraken<sup>a</...
arxiv
other
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true
true
true
2407.13643
Surface roughening in nanoparticle catalysts
[ "Owen Cameron J. ", "Marcella Nicholas ", "O'Connor Christopher R. ", "Kim Taek-Seung ", "Shimogawa Ryuichi ", "Xie Clare Yijia ", "Nuzzo Ralph G. ", "Frenkel Anatoly I. ", "Reece Christian ", "Kozinsky Boris " ]
Supported metal nanoparticle (NP) catalysts are vital for the sustainable production of chemicals, but their design and implementation are limited by the ability to identify and characterize their structures and atomic sites that are correlated with high catalytic activity. Identification of these ''active sites'' ha...
null
2024
2024-07-19 00:00:00
Nanomaterials
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2407.13643v1
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# Surface roughening in nanoparticle catalysts Cameron J. Owen∗,† , 1, 2 Nicholas Marcella<sup>∗</sup> , <sup>3</sup> Christopher R. O'Connor<sup>∗</sup> , 4 Taek-Seung Kim,<sup>4</sup> Ryuichi Shimogawa,5, 6 Clare Yijia Xie,<sup>2</sup> Ralph G. Nuzzo,<sup>3</sup> Anatoly I. Frenkel† , 5, 7 Christian Reece† , <sup>...
arxiv
other
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true
true
true
2407.14181
Harnessing Zn-Volatility for Compositional Tuning in PtZn Nanoalloy Catalysts
[ "Yao Bingqing ", "Xu Chaokai ", "Tang Yaxin ", "Du Yankun ", "Tan Shengdong ", "Dai Sheng ", "Luo Guangfu ", "He Qian " ]
Bimetallic nanoalloys have gained extensive attention due to their tunable properties and wide range of catalytic applications. However, achieving good compositional control in nanoalloy catalysts remains a formidable challenge. In this work, we demonstrate that heat treatment can be used to tune the composition of P...
10.1016/j.nantod.2025.102746
2024
2025-04-15 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2407.14181v1
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# **Harnessing Zn-Volatility for Compositional Tuning in PtZn Nanoalloy Catalysts** Bingqing Yaoa,1,\* , Chaokai Xua,1, Yaxin Tanga,b, Yankun Dua , Shengdong Tan<sup>a</sup> , Sheng Dai<sup>c</sup> , Guangfu Luob , Qian Hea,d,\* a Department of Material Science and Engineering, College of Design and Engineering, Nati...
arxiv
other
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true
false
2408.09355
Atomic Engineering of Triangular Nanopores in Monolayer hBN: A Decoupled Seeding and Growth Approach
[ "Byrne Dana O. ", "Allen Frances I. " ]
Nanopores in 2D materials are of significant interest in advanced membrane technologies aimed at the sensing and separation of ions and molecules. These applications necessitate 2D nanopores that are precise in size and shape, and abundant in number. However, conventional fabrication techniques often struggle to achi...
null
2024
2024-08-20 00:00:00
Nanomaterials
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2408.09355v1
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# Atomic Engineering of Triangular Nanopores in Monolayer hBN: A Decoupled Seeding and Growth Approach Dana O. Byrne<sup>∗</sup>,†,‡,¶ and Frances I. Allen<sup>∗</sup>,‡,¶,§ †Department of Chemistry, University of California, Berkeley, CA, USA ‡Department of Materials Science and Engineering, University of Californi...
arxiv
other
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2409.00789
Living porous ceramics for bacteria-regulated gas sensing and carbon capture
[ "Dutto Alessandro ", "Kan Anton ", "Saraw Zoubeir ", "Maillard Aline ", "Zindel Daniel ", "Studart André R. " ]
Microorganisms hosted in abiotic structures have led to engineered living materials that can grow, sense and adapt in ways that mimic biological systems. Although porous structures should favor colonization by microorganisms, they have not yet been exploited as abiotic scaffolds for the development of living material...
10.1002/adma.202412555
2024
2024-12-12 00:00:00
Ceramics
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2409.00789v1
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### **Living porous ceramics for bacteria-regulated gas sensing and carbon capture** Alessandro Dutto, 1 Anton Kan, 1 Zoubeir Saraw, 1 Aline Maillard, 1 Daniel Zindel, 2 André R. Studart 1 <sup>1</sup> Complex Materials, Department of Materials, ETH Zürich, 8093 Zürich, Switzerland 2 Laboratory of Physical Chemistry, ...
arxiv
other
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true
false
2409.17444
Preparation and Characterization of High Quality Bi1-xSbx Thin Films: A Sputtering Deposition Approach
[ "de Almeida G. G. ", "de Andrade A. M. H. ", "Tumelero M. A. " ]
The Bi1-xSbx was the first 3D topological insulator found in nature. It presents a complex electronic structure with topological to trivial transition and a semimetallic to semiconductor transition, both achieved by changing the x fraction of Sb. The complex nature of this system may lead to several electronic and to...
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2024
2024-09-27 00:00:00
Semiconductors
http://creativecommons.org/licenses/by-sa/4.0/
http://arxiv.org/pdf/2409.17444v1
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# Preparation and Characterization of High Quality Bi1−*x*Sb*<sup>x</sup>* Thin Films: A Sputtering Deposition Approach de Almeida G. G.,<sup>1</sup> de Andrade A. M. H.,<sup>1</sup> and Tumelero, M. A.<sup>1</sup> *Physics Institute, Federal University of Rio Grande do Sul, Av. Bento Gon¸calves 9500, Porto Alegre, 9...
arxiv
other
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2410.01439
Graphene MEMS and NEMS
[ "Fan Xuge ", "He Chang ", "Ding Jie ", "Gao Qiang ", "Ma Hongliang ", "Lemme Max C. ", "Zhang Wendong " ]
Graphene is being increasingly used as an interesting transducer membrane in micro- and nanoelectromechanical systems (MEMS and NEMS, respectively) due to its atomical thickness, extremely high carrier mobility, high mechanical strength and piezoresistive electromechanical transductions. NEMS devices based on graphen...
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2024
2024-10-03 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by-nc-sa/4.0/
http://arxiv.org/pdf/2410.01439v1
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# **Graphene MEMS and NEMS** Xuge Fan1,2,3\*, Chang He1 , Jie Ding3\* , Qiang Gao1 , Hongliang Ma1,3, Max C. Lemme4,5 and Wendong Zhang6,7\* 1 Advanced Research Institute of Multidisciplinary Sciences, Beijing Institute of Technology, 100081 Beijing, China. 2 Center for Interdisciplinary Science of Optical Quantum a...
arxiv
other
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2410.06133
Control of Cu morphology on TaN barrier and combined Ru-TaN barrier/liner substrates for nanoscale interconnects from atomistic kinetic Monte Carlo simulations
[ "Aldana Samuel ", "Nies Cara-Lena ", "Nolan Michael " ]
The miniaturization of electronic devices brings severe challenges in the deposition of metal interconnects in back end of line processing due to a continually decreasing volume available for metal deposition in the interconnect via. Cu is currently used as the interconnect metal and requires barrier and liner layers...
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2024
2024-10-10 00:00:00
Metals
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2410.06133v1
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# Control of Cu morphology on TaN barrier and combined Ru-TaN barrier/liner substrates for nanoscale interconnects from atomistic kinetic Monte Carlo simulations *Samuel Aldana\*, Cara-Lena Nies, Michael Nolan\** Tyndall National Institute, University College Cork, Lee Maltings, Dyke Parade, Cork T12 R5CP, Ireland E...
arxiv
other
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2410.06489
High proton conductivity through angstrom-porous titania
[ "Ji Y. ", "Hao G. -P. ", "Tan Y. -T. ", "Xiong W. Q. ", "Liu Y. ", "Zhou W. Z. ", "Tang D. -M. ", "Ma R. Z. ", "Yuan S. J. ", "Sasaki T. ", "Lozada-Hidalgo M. ", "Geim A. K. ", "Sun Pengzhan " ]
Two dimensional (2D) crystals have attracted strong interest as a new class of proton conducting materials that can block atoms, molecules and ions while allowing proton transport through the atomically thin basal planes. Although 2D materials exhibit this perfect selectivity, the reported proton conductivities have ...
10.1038/s41467-024-54544-z
2024
2024-12-09 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by-nc-sa/4.0/
http://arxiv.org/pdf/2410.06489v1
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# High proton conductivity through angstrom-porous titania Y. Ji<sup>1</sup> , G.-P. Hao<sup>2</sup> , Y.-T. Tan3,4, W. Q. Xiong5,6 , Y. Liu<sup>1</sup> , W. Z. Zhou<sup>1</sup> , D.-M. Tang<sup>7</sup> , R. Z. Ma<sup>7</sup> , S. J. Yuan<sup>6</sup> , T. Sasaki<sup>7</sup> , M. Lozada-Hidalgo3,4, A. K. Geim3,4, P. Z....
arxiv
other
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2410.11264
Change in Magnetic Order in NiPS3 Single Crystals Induced by a Molecular Intercalation
[ "Chakraborty Nirman ", "Harchol Adi ", "Abu-Hariri Azhar ", "Yadav Rajesh Kumar ", "Dawod Muhamed ", "Gaonkar Diksha Prabhu ", "Sharma Kusha ", "Eyal Anna ", "Amouyal Yaron ", "Naveh Doron ", "Lifshitz Efrat " ]
Intercalation is a robust method for tuning the physical properties of a vast number of van der Waals (vdW) materials. However, the prospects of using intercalation to modify magnetism in vdWs systems and the associated mechanisms have not been investigated adequately. In this work, we modulate magnetic order in an X...
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2024
2024-10-16 00:00:00
Magnetic
http://creativecommons.org/licenses/by-nc-sa/4.0/
http://arxiv.org/pdf/2410.11264v1
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# **Change in Magnetic Order in NiPS<sup>3</sup> Single Crystals Induced by a Molecular Intercalation** Nirman Chakraborty,<sup>1</sup> Adi Harchol,<sup>1</sup> Azhar Abu-Hariri,<sup>1</sup> Rajesh Kumar Yadav,2,3 Muhamed Dawod,<sup>4</sup>Diksha Prabhu Gaonkar, <sup>1</sup>Kusha Sharma,<sup>1</sup> Anna Eyal,<sup>5</...
arxiv
other
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2412.18722
Photoreforming of plastic waste into valuable products and hydrogen using a high-entropy oxynitride with distorted atomic-scale structure
[ "Hai Ho Truong Nam ", "Nguyen Thanh Tam ", "Nishibori Maiko ", "Ishihara Tatsumi ", "Edalati Kaveh " ]
The persistent existence of plastic waste causes serious problems for the environment, directly and indirectly affecting the health of organisms and humans. Photoreforming is a nature-friendly method that only uses solar energy to convert plastic waste into green hydrogen (H2) and valuable organic products. This stud...
10.1016/j.apcatb.2024.124968
2024
2024-12-30 00:00:00
Ceramics
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2412.18722v1
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# **Photoreforming of plastic waste into valuable products and hydrogen using a high-entropy oxynitride with distorted atomic-scale structure** Ho Truong Nam Haia,b, Thanh Tam Nguyena,c, Maiko Nishibori<sup>d</sup> , Tatsumi Ishiharaa,c,e, Kaveh Edalatia,b,c,\* - <sup>a</sup> WPI, International Institute for Carbon N...
arxiv
other
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2412.19633
High performance Black Phosphorus/Graphitic Carbon Nitride Heterostructure-based Wearable Sensor for Real-time Sweat Glucose Monitoring
[ "Ozkahraman Ecem Ezgi ", "Eroglu Zafer ", "Efremov Vladimir ", "Maryyam Arooba ", "Abbasiasl Taher ", "Das Ritu ", "Mirzajani Hadi ", "Hanedar Berna Akgenc ", "Beker Levent ", "Metin Onder " ]
Wearable, non-invasive glucose sensors capable of accurate and continuous monitoring are crucial for managing metabolic conditions yet achieving high sensitivity and stability in these devices remains challenging. In this work, we present a Black Phosphorus/Graphitic Carbon Nitride (BP/g-CN) heterostructure engineere...
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2024
2024-12-30 00:00:00
Nanomaterials
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2412.19633v1
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# **High performance Black Phosphorus/Graphitic Carbon Nitride Heterostructure-based Wearable Sensor for Real-time Sweat Glucose Monitoring** Ecem Ezgi Özkahramana,b, Zafer Eroğlu<sup>b</sup> , Vladimir Efremov<sup>b</sup> , Arooba Maryyam<sup>c</sup> , Taher Abbasiasl<sup>d</sup> , Ritu Das<sup>e</sup> , Hadi Mirzaja...
arxiv
other
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2501.05090
Migration of phthalate plasticisers in heritage objects made of poly(vinyl chloride): mechanical and environmental aspects
[ "Bujok Sonia ", "Pańczyk Tomasz ", "Szutkowski Kosma ", "Anioł Dominika ", "Antropov Sergii ", "Kruczała Krzysztof ", "Bratasz Łukasz " ]
To clean or not to clean? The solution to this dilemma is related to understanding the plasticiser migration which has a few practical implications for the state of museum artefacts made of plasticised poly(vinyl chloride) - PVC and objects stored in their vicinity. The consequences of this process encompass aestheti...
10.1016/j.jenvman.2025.124234
2025
2025-01-24 00:00:00
Polymers
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2501.05090v1
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# Migration of phthalate plasticisers in heritage objects made of poly(vinyl chloride): mechanical and environmental aspects Sonia Bujoka\* , Tomasz Pańczyk<sup>a</sup> , Kosma Szutkowski<sup>b</sup> , Dominika Anioł<sup>b</sup> , Sergii Antropov<sup>a</sup> , Krzysztof Kruczała<sup>c</sup> , Łukasz Bratasz<sup>a</sup...
arxiv
other
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2501.10015
Phase and sulfur vacancy engineering in cadmium sulfide for boosting hydrogen production from catalytic plastic waste photoconversion
[ "Nguyen Thanh Tam GPM", "Hidalgo-Jiménez Jacqueline GPM", "Sauvage Xavier GPM", "Saito Katsuhiko WPI-I2CNER", "Guo Qixin WPI-I2CNER", "Edalati Kaveh WPI-I2CNER" ]
Cadmium sulfide (CdS) is a well-known low-bandgap photocatalyst, but its efficiency is often hindered by rapid photo-generated carrier recombination and a limited number of active catalytic sites. To overcome these challenges, this study introduces an efficient CdS photocatalyst through a novel strategy combining met...
10.1016/j.cej.2024.158730
2025
2025-01-20 00:00:00
Semiconductors
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2501.10015v1
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## **Chemical Engineering Journal, Vol. 504, p. 158730, 2025 https://doi.org/10.1016/j.cej.2024.158730** ## **Phase and sulfur vacancy engineering in cadmium sulfide for boosting hydrogen production from catalytic plastic waste photoconversion** Thanh Tam Nguyena,b , Jacqueline Hidalgo-Jiméneza,c , Xavier Sauvage<sup...
arxiv
other
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2501.11026
Revealing the role played by $\alpha$- and $\beta$-relaxation in hydrostatically compressed metallic glasses
[ "Shen Jie ", "Cornet Antoine ", "Ronca Alberto ", "Pineda Eloi ", "Yang Fan ", "Garden Jean-Luc ", "Moiroux Gael ", "Vaughan Gavin ", "di Michiel Marco ", "Garbarino Gaston ", "Westermeier Fabian ", "Goujon Celine ", "Legendre Murielle ", "Liu Jiliang ", "Cangialosi Daniele ", "Ruta Be...
Any property of metallic glasses is controlled by the microscopic ongoing relaxation processes. While the response of these processes to temperature is well documented, little is known on their pressure dependence, owning to non-trivial experimental challenges. By combining fast differential scanning calorimetry, X-r...
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2025
2025-01-22 00:00:00
Metals
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2501.11026v1
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# **Revealing the role played by** *α***- and** *β***-relaxation in hydrostatically compressed metallic glasses** **Jie Shen1,2†\*, Antoine Cornet1,2†, Alberto Ronca1,2, Eloi Pineda<sup>3</sup> , Fan Yang<sup>4</sup> , Jean-Luc Garden<sup>1</sup> , Gael Moiroux<sup>1</sup> , Gavin Vaughan<sup>2</sup> , Marco di Michie...
arxiv
other
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2501.12677
Quantum Emitters in Hexagonal Boron Nitride: Principles, Engineering and Applications
[ "Mai Thi Ngoc Anh ", "Hossain Md Shakhawath ", "Nguyen Nhat Minh ", "Chen Yongliang ", "Chen Chaohao ", "Xu Xiaoxue ", "Trinh Quang Thang ", "Dinh Toan ", "Tran Toan Trong " ]
Solid-state quantum emitters, molecular-sized complexes releasing a single photon at a time, have garnered much attention owing to their use as a key building block in various quantum technologies. Among these, quantum emitters in hexagonal boron nitride (hBN) have emerged as front runners with superior attributes co...
null
2025
2025-01-23 00:00:00
Nanomaterials
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2501.12677v1
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# **Quantum Emitters in Hexagonal Boron Nitride: Principles, Engineering and Applications** *Thi Ngoc Anh Mai, Md Shakhawath Hossain, Nhat Minh Nguyen, Yongliang Chen, Chaohao Chen, Xiaoxue Xu, Quang Thang Trinh, Toan Dinh, Toan Trong Tran\** Thi Ngoc Anh Mai, Md Shakhawath Hossain, Nhat Minh Nguyen, Toan Trong Tran ...
arxiv
other
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2501.13245
Accelerating Discovery of Solid-State Thin-Film Metal Dealloying for 3D Nanoarchitecture Materials Design through Laser Thermal Gradient Treatment
[ "Chung Cheng-Chu ", "Li Ruipeng ", "Veith Gabriel M. ", "Zhang Honghu ", "Camino Fernando ", "Lu Ming ", "Tiwale Nikhil ", "Zhang Sheng ", "Yager Kevin ", "Chen-Wiegart Yu-chen Karen " ]
Thin-film solid-state metal dealloying (thin-film SSMD) is a promising method for fabricating nanostructures with controlled morphology and efficiency, offering advantages over conventional bulk materials processing methods for integration into practical applications. Although machine learning (ML) has facilitated th...
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2025
2025-01-24 00:00:00
Nanomaterials
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2501.13245v1
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## **Accelerating Discovery of Solid-State Thin-Film Metal Dealloying for 3D Nanoarchitecture** ## **Materials Design through Laser Thermal Gradient Treatment** Cheng-Chu Chung<sup>1</sup> , Ruipeng Li<sup>2</sup> , Gabriel M. Veith<sup>3</sup> , Honghu Zhang<sup>2</sup> , Fernando Camino<sup>4</sup> , Ming Lu<sup>4<...
arxiv
other
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true
2501.16242
Transition Metal-Driven Variations in Structure, Magnetism, and Photocatalysis of Monoclinic M3Se4 (M = Fe, Co, Ni) Nanoparticles
[ "Ghalawat Monika CSIR-National Chemical Laboratory, Academy of\n Scientific and Innovative Research", "Chauhan Inderjeet CSIR-National Chemical Laboratory, Academy of\n Scientific and Innovative Research", "Singh Dinesh CSIR-National Chemical Laboratory, Academy of\n Scientific and Innovative Research", ...
The transition metal selenides (MxSey) have gained attention for their unique physical and chemical properties, especially those associated with the transition metal (M). Despite advancements in synthesis, fabricating these selenides is challenging due to their complex stoichiometry and high asymmetry. One such syste...
null
2025
2025-01-28 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2501.16242v1
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# **Transition Metal-Driven Variations in Structure, Magnetism, and Photocatalysis of Monoclinic M₃Se₄ (M = Fe, Co, Ni) Nanoparticles** Monika Ghalawat*†,‡*, Inderjeet Chauhan*†,‡*, Dinesh Singh*†,‡* , [Chinnakonda S.](https://pubs.rsc.org/en/results?searchtext=Author%3AChinnakonda%20S.%20Gopinath) [Gopinath](https:/...
arxiv
other
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2502.05940
Various Architectures of Colloidal Cu3(MoO4)2(OH)2 and Cu3Mo2O9; Thermal Stability, Photoluminescence and Magnetic Properties of Cu3(MoO4)2(OH)2 and Cu3Mo2O9 Nanosheets
[ "Bayat Azam ", "Mahjoub Ali Reza ", "Amini Mostafa M. " ]
The lindgrenite compounds [Cu3(MoO4)2(OH)2] with various architectures and high crystallinity were prepared by a simple surfactant-assisted hydrothermal method. Then, the Cu3Mo2O9 samples were prepared by calcination of the as-synthesized Cu3(MoO4)2(OH)2. The resulting samples have high crystallinity, colloidal prope...
null
2025
2025-02-11 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2502.05940v1
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# **Various Architectures of Colloidal Cu3(MoO4)2(OH)<sup>2</sup> and Cu3Mo2O9; Thermal Stability,** **Photoluminescence and Magnetic Properties of Cu3(MoO4)2(OH)<sup>2</sup> and Cu3Mo2O<sup>9</sup>** ### **Nanosheets** Azam Bayat a, \*, Ali Reza Mahjoub <sup>a</sup> , Mostafa M. Amini<sup>b</sup> *<sup>a</sup>Depa...
arxiv
other
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2502.06495
Resonant spin amplification and accumulation in MAPbI$_3$ single crystals
[ "Kirstein Erik ", "Yakovlev Dmitri R. ", "Zhukov Evgeny A. ", "Kopteva Nataliia E. ", "Turedi Bekir ", "Kovalenko Maksym V. ", "Bayer Manfred " ]
Quantum technologic and spintronic applications require reliable semiconducting materials that enable a significant, long-living spin polarization of electronic excitations and offer the ability to manipulate it optically in an external field. Due to the specifics of band structure and remarkable spin-dependent prope...
null
2025
2025-02-11 00:00:00
Semiconductors
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2502.06495v1
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# Resonant spin amplification and accumulation in MAPbI<sup>3</sup> single crystals Erik Kirstein<sup>1</sup> , Dmitri R. Yakovlev<sup>1</sup> , Evgeny A. Zhukov<sup>1</sup> , Nataliia E. Kopteva<sup>1</sup> , Bekir Turedi2,<sup>3</sup> , Maksym V. Kovalenko2,<sup>3</sup> , Manfred Bayer1,<sup>4</sup> <sup>1</sup>Ex...
arxiv
other
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false
2502.08750
Tuning electrochemical properties and thermal stability of YSZ mesoporous thin films for SOFC applications
[ "Sievers Bernardo ", "Granja Leticia ", "Zelcer Andrés ", "Juan Dilson ", "Ferrari Valeria ", "Passanante Sebastián ", "Lombardo Verónica ", "Fuertes María Cecilia ", "Fuentes Rodolfo Oscar ", "Sacanell Joaquín " ]
Dense and mesoporous 4% mol Yttria-stabilized zirconia thin films were deposited on amorphous silica substrates. The effects of the temperature on the mesostructure were analyzed, by applying different thermal treatments to the samples within the range of SOFC operation conditions. Electrochemical impedance spectrosc...
10.1021/acsaem.4c02375
2025
2025-02-14 00:00:00
Ceramics
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2502.08750v1
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# Tuning electrochemical properties and thermal stability of YSZ mesoporous thin films for SOFC applications B. Sievers, L. Granja, A. Zelcer, D. Juan., V. Ferrari, S. Passanante, V. Lombardo, M. C. Fuertes, R. Fuentes, J. Sacanell ## Abstract: Dense and mesoporous 4% mol Yttria-stabilized zirconia thin films were d...
arxiv
other
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true
2502.12612
Study of amorphous alumina coatings for next-generation nuclear reactors: hightemperature in-situ and post-mortem Raman spectroscopy and X-ray diffraction
[ "Gaweda Magdalena ", "Jelen Piotr ", "Zaborowska Agata ", "Diduszko Ryszard ", "Kurpaska Lukasz " ]
The present work focuses on the investigation of the thermal stability and structural integrity of amorphous alumina coatings intended for use as protective coatings on cladding tubes in Generation IV nuclear reactors, specifically in the Lead-cooled Fast Reactor (LFR) type. Hightemperature Raman spectroscopy and hig...
null
2025
2025-02-19 00:00:00
Ceramics
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2502.12612v1
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![](_page_0_Picture_0.jpeg) ![](_page_0_Picture_1.jpeg) This work was carried out in whole or in part within the framework of the NOMATEN Centre of Excellence, supported from the European Union Horizon 2020 research and innovation program (Grant Agreement No. 857470) and from the European Regional Development Fund vi...
arxiv
other
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2502.12705
2D Layered Heterojunctions for Photoelectrocatalysis
[ "Wang Mengjiao ", "Langer Michal ", "Altieri Roberto ", "Crisci Matteo ", "Osella Silvio ", "Gatti Teresa " ]
Two-dimensional (2D) layered nanomaterials heterostructures, arising from the combination of 2D materials with other low-dimensional species, feature large surface area to volume ratio, which provides a high density of active sites for catalytic ap-plications and in particular for (photo)electrocatalysis (PEC). Meanw...
10.1021/acsnano.3c12274
2025
2025-02-19 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2502.12705v1
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# **2D Layered Heterojunctions for Photoelectrocatalysis** Mengjiao Wang\*, Michal Langer, Roberto Altieri, Matteo Crisci, Silvio Osella\* and Teresa Gatti\* *KEYWORDS: 2D layered nanostructures, heterojunctions, photoelectrocatalysis, light energy conversion* **ABSTRACT:** Two-dimensional (2D) layered nanomaterials ...
arxiv
other
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false
2502.15497
Thermally-induced microstructural evolution in nanoparticle-based CuO, WO$_3$ and CuO-WO$_3$ thin films for hydrogen gas sensing
[ "Shaji Kalyani ", "Haviar Stanislav ", "Zeman Petr ", "Procházka Michal ", "Čerstvý Radomír ", "Kumar Nirmal ", "Čapek Jiří " ]
This study systematically investigates the microstructural evolution of nanoparticle-based CuO, WO$_3$, and composite 'CuO-WO$_3$' thin films induced by their post-deposition annealing. The films were reactively deposited using a magnetron-based gas aggregation technique, with the composite films consisting of altern...
null
2025
2025-02-24 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2502.15497v1
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# Highlights #### **Thermally-induced microstructural evolution in nanoparticle-based CuO, WO**<sup>3</sup> **and CuO– WO**<sup>3</sup> **thin films for hydrogen gas sensing** Kalyani Shaji,Stanislav Haviar,Petr Zeman,Michal Procházka,Radomír Čerstvý,Nirmal Kumar,Jiří Čapek - Reactive synthesis of nanoparticle-based...
arxiv
other
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true
2502.17112
Defects in the $\beta$-Ga$_2$O$_3$($\bar201$)/HfO$_2$ MOS system and the effect of thermal treatments
[ "Agrawal Khushabu. S. ", "LaTorraca Paolo ", "Valentijn Jonas ", "Hawkins Roberta ", "Gruszecki Adam A. ", "Roy Joy ", "Lebedev Vasily ", "Jones Lewys ", "Wallace Robert M. ", "Young Chadwin D. ", "Hurley Paul K. ", "Cherkaoui Karim " ]
We have investigated the properties of the $\beta$-Ga$_2$O$_3$($\bar201$)/HfO$_2$/Cr/Au MOS (metal-oxide-semiconductor) system after annealing (450$^\circ$C) in different ambient conditions (forming gas, N$_2$ and O$_2$). Defect properties have been analyzed using an approach combining experimental impedance measurem...
null
2025
2025-02-26 00:00:00
Semiconductors
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2502.17112v1
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# Defects in the β-Ga2O3(2̅01)/HfO<sup>2</sup> MOS system and the effect of thermal treatments *Khushabu. S. Agrawal<sup>1</sup> , Paolo LaTorraca<sup>1</sup> , Jonas Valentijn<sup>1</sup> , Roberta Hawkins<sup>2</sup><sup>ǂ</sup> , Adam A. Gruszecki<sup>2</sup> , Joy Roy<sup>2</sup> , Vasily Lebedev<sup>3</sup> , Lew...
arxiv
other
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false
2503.12889
Reversing Hydrogen-Related Loss in $\alpha$-Ta Thin Films for Quantum Device Fabrication
[ "Lozano D. P. ", "Mongillo M. ", "Raes B. ", "Canvel Y. ", "Massar S. ", "Vadiraj A. M. ", "Ivanov Ts. ", "Acharya R. ", "Van Damme J. ", "Van de Vondel J. ", "Wan D. ", "Potocnik A. ", "De Greve K. " ]
$\alpha$-Tantalum ($\alpha$-Ta) is an emerging material for superconducting qubit fabrication due to the low microwave loss of its stable native oxide. However, hydrogen absorption during fabrication, particularly when removing the native oxide, can degrade performance by increasing microwave loss. In this work, we d...
null
2025
2025-03-18 00:00:00
Superconductors
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2503.12889v2
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# Reversing Hydrogen-Related Loss in α-Ta Thin Films for Quantum Device Fabrication D. P. Lozano1 , M. Mongillo1 , B. Raes1 , Y. Canvel1 , S. Massar1 , A. M. Vadiraj1 , Ts. Ivanov1 , R. Acharya1 , J. Van Damme1,2, J. Van de Vondel3 , D. Wan1 , A. Potočnik<sup>1</sup> , and K. De Greve1,2 1 Imec, Kapeldreef 75, Leuven...
arxiv
other
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2503.13142
Effects of Disorder on the Energy Landscape and Motional Mechanisms Involved in Lithium Ion Dynamics and Transport in Solid Electrolytes: Li5.5PS4.5Cl1.5 Argyrodite as a Case Study
[ "Badragheh Mohammad Ali ", "Miß Vanessa ", "Roling Bernhard ", "Vogel Michael " ]
7Li NMR diffusometry and relaxometry are combined with electrochemical impedance spectroscopy to compare the mechanisms for the dynamics and transport of lithium ions in disordered and crystalline electrolytes with argyrodite composition Li5.5PS4.5Cl1.5. The dc conductivity of a disordered sample prepared by ball mil...
null
2025
2025-03-18 00:00:00
Ceramics
http://arxiv.org/licenses/nonexclusive-distrib/1.0/
http://arxiv.org/pdf/2503.13142v1
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# **Effects of Disorder on the Energy Landscape and Motional Mechanisms Involved in Lithium Ion Dynamics and Transport in Solid Electrolytes: Li5.5PS4.5Cl1.5 Argyrodite as a Case Study** Mohammad Ali Badragheh,<sup>a</sup> Vanessa Miß, <sup>b</sup> Bernhard Roling,<sup>b</sup> Michael Vogela,\* a Institute for Conden...
arxiv
other
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null
true
true
true
2503.14069
Sustainable wafer-scale integration of epitaxial ZnO on silicon for piezoelectric devices
[ "Sanchez-Fuentes D. ", "Desgarceaux R. ", "Rahal A. ", "Garcia L. ", "Bousri S. ", "Ding S. ", "Camara N. ", "Pascal F. ", "Garcia-Bermejo R. ", "Guillaume N. ", "Ardila G. ", "Gazquez J. ", "Magen C. ", "Plana-Ruiz S ", "Guasch C. ", "Carretero-Genevrier A. " ]
To sustainably support the ongoing energetic transition, we need functional metal oxides capable of converting energy, and produce storage, and sensing devices. However, these materials suffer from a high economic cost of manufacturing, and their production in a sustainable way is, to date, a milestone. Additionally,...
null
2025
2025-03-19 00:00:00
Semiconductors
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2503.14069v1
null
null
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null
# Sustainable wafer-scale integration of epitaxial ZnO on silicon for piezoelectric devices *D. Sanchez-Fuentes<sup>1</sup> , R. Desgarceaux<sup>1</sup> , A. Rahal<sup>1</sup> , L. García<sup>1</sup> , S. Bousri<sup>1</sup> , S. Ding<sup>1</sup> , N. Camara1,2 ,* *F. Pascal<sup>1</sup> , R. García-Bermejo<sup>1</sup...
arxiv
other
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null
true
true
false
2503.15799
Photocatalytic Carbon Dioxide Methanation by High-Entropy Oxides: Significance of Work Function
[ "Hidalgo-Jiménez Jacqueline ", "Akbay Taner ", "Sauvage Xavier ", "Ishihara Tatsumi ", "Edalati Kaveh " ]
Methane (CH4) formation from photocatalytic carbon dioxide (CO2) conversion in water is currently of interest because methane is a fuel, and it can also be transformed into other useful hydrocarbons. However, achieving high selectivity to produce methane remains a challenge because of the large number of contributing...
10.1016/j.apcatb.2025.125259
2025
2025-03-21 00:00:00
Ceramics
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2503.15799v1
null
null
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null
# **Photocatalytic Carbon Dioxide Methanation by High-Entropy Oxides: Significance of Work Function** Jacqueline Hidalgo-Jiménez1,2, Taner Akbay<sup>3</sup> , Xavier Sauvage<sup>4</sup> , Tatsumi Ishihara1,5 and Kaveh Edalati1,5,\* - <sup>1</sup> WPI, International Institute for Carbon Neutral Energy Research (WPI-I2...
arxiv
other
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true
true
false
2503.22476
The 2D Materials Roadmap
[ "Ren Wencai ", "Bøggild Peter ", "Redwing Joan ", "Novoselov Kostya ", "Sun Luzhao ", "Qi Yue ", "Jia Kaicheng ", "Liu Zhongfan ", "Burton Oliver ", "Alexander-Webber Jack ", "Hofmann Stephan ", "Cao Yang ", "Long Yu ", "Yang Quan-Hong ", "Li Dan ", "Choi Soo Ho ", "Kim Ki Kang ", ...
Over the past two decades, 2D materials have rapidly evolved into a diverse and expanding family of material platforms. Many members of this materials class have demonstrated their potential to deliver transformative impact on fundamental research and technological applications across different fields. In this roadma...
null
2025
2025-03-31 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2503.22476v2
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# 2D Materials Roadmap # The 2025 2D Materials Roadmap Wencai Ren1\*, Peter Bøggild2\*, Joan Redwing3\*, Kostya Novoselov4,5, Luzhao Sun<sup>6</sup> , Yue Qi<sup>6</sup> , Kaicheng Jia<sup>6</sup> , Zhongfan Liu<sup>6</sup> , Oliver Burton<sup>7</sup> , Jack Alexander-Webber<sup>7</sup> , Stephan Hofmann<sup>7</sup> ...
arxiv
other
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null
true
true
false
2503.23778
Efficient defect healing of single-walled cabron nanotubes through $ \mathrm{C}_{2}\mathrm{H}_{2} $-assisted multiple-cycle treatment with air exposure
[ "Shen Man ", "Inoue Taiki ", "Wang Mengyue ", "Liu Yuanjia ", "Kobayashi Yoshihiro " ]
Defects in single-walled carbon nanotubes (SWCNTs) degrade their mechanical,electrical, and thermal properties, limiting their potential applications. To realize the diverse applications of SWCNTs, it is essential to enhance their crystallinity through effective defect healing. However, traditional thermal treatments...
10.1021/acsami.5c00619
2025
2025-04-01 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by-nc-sa/4.0/
http://arxiv.org/pdf/2503.23778v1
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# Efficient defect healing of single-walled carbon nanotubes through C2H2-assisted multiple-cycle treatment with air exposure Man Shen,<sup>∗</sup> Taiki Inoue, Mengyue Wang, Yuanjia Liu, and Yoshihiro Kobayashi<sup>∗</sup> Department of Applied Physics, Osaka University, Suita, Osaka, 565-0871, Japan E-mail: [shen....
arxiv
other
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null
true
true
false
2504.00350
Chemical and Morphological Transformations of a Ag-Cu Nanocatalyst During CO2 Reduction Reaction
[ "Girotto Gustavo Zottis ", "Jaugstetter Maximilian ", "Kim Dongwoo ", "Martins Ruan M. ", "Muniz André R. ", "Salmeron Miquel ", "Nemsak Slavomir ", "Bernardi Fabiano " ]
The conversion of CO2 into high-value chemicals through a photoreduction reaction in water is a promising route to reduce the dependence on fossil fuels. Ag nanoparticles can drive this reaction via localized surface plasmon resonance, but their low selectivity limits usage in industry. Enhancing selectivity toward h...
null
2025
2025-04-02 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2504.00350v1
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null
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null
# Chemical and Morphological Transformations of a Ag-Cu Nanocatalyst During CO2 Reduction Reaction Gustavo Zottis Girotto,1,2 Maximilian Jaugstetter,<sup>3</sup> Dongwoo Kim,2,4 Ruan M. Martins,<sup>5</sup> André R. Muniz,<sup>5</sup> Miquel Salmeron,<sup>3</sup> Slavomir Nemsak,2,6,\* Fabiano Bernardi1,\* <sup>1</su...
arxiv
other
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null
true
true
false
2504.05189
Influence of pore-confined water on the thermal expansion of a zinc-based metal-organic framework
[ "Strasser Nina ", "Schrode Benedikt ", "Torvisco Ana ", "John Sanjay ", "Kunert Birgit ", "Bitschnau Brigitte ", "Lindner Florian Patrick ", "Slugovc Christian ", "Zojer Egbert ", "Resel Roland " ]
Understanding the reversible intercalation of guest molecules into metal-organic frameworks is crucial for advancing their design for practical applications. In this work, we explore the impact of H$_{\mathrm{2}}\!$O as a guest molecule on the thermal expansion of the zinc-based metal-organic framework GUT-2. Dehydra...
null
2025
2025-04-08 00:00:00
Metal-organic frameworks
http://creativecommons.org/licenses/by/4.0/
http://arxiv.org/pdf/2504.05189v1
null
null
null
null
# ARTICLE Received 00th January 20xx, Accepted 00th January 20xx DOI: 10.1039/x0xx00000x # **Influence of pore-confined water on the thermal expansion of a zinc-based metal-organic framework** Nina Strasser, <sup>a</sup> Benedikt Schrode,b Ana Torvisco,c Sanjay John, <sup>a</sup> Birgit Kunert, <sup>a</sup> Brigitt...
arxiv
other
null
null
true
true
true
2504.07404
Catalight -- an open source automated photocatalytic reactor package illustrated through plasmonic acetylene hydrogenation
[ "Bourgeois B. B. ", "Dai A. X. ", "Carlin C. C. ", "Yuan L. ", "Al-Zubeidi A. ", "Cheng W-H. ", "Swearer D. F. ", "Dionne J. A. " ]
An open-source and modular Python package, Catalight, is developed and demonstrated to automate (photo)catalysis measurements. (Photo)catalysis experiments require studying several parameters to evaluate performance, including temperature, gas flow rate and composition, illumination power, and spectral profile. Catal...
null
2025
2025-04-11 00:00:00
Nanomaterials
http://creativecommons.org/licenses/by-nc-nd/4.0/
http://arxiv.org/pdf/2504.07404v1
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# Catalight – an open source automated photocatalytic reactor package illustrated through plasmonic acetylene hydrogenation B. B. Bourgeois,\*[a][α] A. X. Dai,[a] C. C. Carlin,[a] L. Yuan,[a] A. Al-Zubeidi, [a][β] W-H. Cheng,[b] D. F. Swearer,[c] J. A. Dionne\*[a] An open-source and modular Python package, Catalight,...
arxiv
other
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null
true
true
true
cond-mat/0108371
Template-Directed Self-Assembly of Buried Nanowires and the Pearling Instability
[ "Mueller T. ", "Heinig K. -H. ", "Schmidt B. " ]
The fabrication of more and more miniaturized electronic and photonic devices relies on new, ingenious methods for the fabrication of spatially controlled nanostructures. Examples are electronic devices based on semiconducting nanowires and photonic devices based on chains of metallic nanoclusters that guide light by...
null
2001
2007-05-23 00:00:00
Nanomaterials
null
http://arxiv.org/pdf/cond-mat/0108371v1
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null
# Template-Directed Self-Assembly of Buried Nanowires and the Pearling Instability T. M¨uller, K.-H. Heinig, B. Schmidt<sup>∗</sup> Forschungszentrum Rossendorf, Institut f¨ur Ionenstrahlphysik und Materialforschung, PO-BOX 51 01 19, 01314 Dresden, Germany (Dated: February 1, 2008) The fabrication of more and more ...
arxiv
other
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null
true
true
false
cond-mat/0201502
p-Type semiconducting properties in lithium-doped MgO single crystals
[ "Tardio M. M. ", "Ramirez R. ", "Gonzalez R. ", "Chen Y. " ]
The phenomenally large enhancement in conductivity observed when Li-doped MgO crystals are oxidized at elevated temperatures was investigated by dc and ac electrical measurements in the temperature interval 250-673 K. The concentration of ([Li]^{0}) centers (Li^{+} ions each with a trapped hole) resulting from oxidat...
10.1103/PhysRevB.66.134202
2002
2009-11-07 00:00:00
Ceramics
null
http://arxiv.org/pdf/cond-mat/0201502v1
null
null
null
null
# p -TYPE SEMICONDUCTING PROPERTIES IN LITHIUM-DOPED MgO SINGLE CRYSTALS M. M. Tard´ıo,[∗](#page-1-0) R. Ram´ırez,[†](#page-1-0) and R. Gonz´alez Departamento de F´ısica, Escuela Polit´ecnica Superior, Universidad Carlos III, Avda. de la Universidad, 30, 28911 Legan´es, Madrid, Spain Y. Chen Division of Materials S...
arxiv
other
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null
true
true
true
cond-mat/0205560
Properties of Ferromagnetic Ga1-xMnxN Films Grown by Ammonia-MBE
[ "Sonoda Saki ", "Hori Hidenobu ", "Yamamoto Yoshiyuki ", "Sasaki Takahiko ", "Sato Masugu ", "Shimizu Saburo ", "Suga Ken-ichi ", "Kindo Koichi " ]
Using ammonia as nitrogen source for molecular beam epitaxy, the GaN-based diluted magnetic semiconductor Ga1-xMnxN is successfully grown with Mn concentration up to x~6.8% and with p-type conductivity. The films have wurtzite structure with substitutional Mn on Ga site in GaN. Magnetization measurements revealed tha...
10.1109/TMAG.2002.803147
2002
2009-11-07 00:00:00
Semiconductors
null
http://arxiv.org/pdf/cond-mat/0205560v1
null
null
null
null
# Properties of Ferromagnetic Ga1-xMnxN Films Grown by Ammonia-MBE Saki Sonoda, Hidenobu Hori, Yoshiyuki Yamamoto, Takahiko Sasaki, Masugu Sato, Saburo Shimizu, Ken-ichi Suga and Koichi Kindo *Abstract***—Using ammonia as nitrogen source for molecular beam epitaxy, the GaN-based diluted magnetic semiconductor Ga1-xMn...
arxiv
other
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null
true
true
false
cond-mat/0205575
The role of the alloy structure in the magnetic behavior of granular systems
[ "Bastos C. S. M. Instituto de\n Fisica, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ, Brazil", "Bahiana M. Instituto de\n Fisica, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ, Brazil", "Nunes W. C. Instituto de\n Fisica, Universidade Federal do Rio de Janeiro, Rio de Janeiro, R...
The effect of grain size, easy magnetization axis and anisotropy constant distributions in the irreversible magnetic behavior of granular alloys is considered. A simulated granular alloy is used to provide a realistic grain structure for the Monte Carlo simulation of the ZFC-FC curves. The effect of annealing and ext...
10.1103/PhysRevB.66.214407
2002
2009-11-07 00:00:00
Nanomaterials
null
http://arxiv.org/pdf/cond-mat/0205575v1
null
null
null
null
# The role of the alloy structure in the magnetic behavior of granular systems C. S. M. Bastos, M. Bahiana, W. C. Nunes and M. A. Novak Instituto de F´ısica, Universidade Federal do Rio de Janeiro Caixa Postal 68528, Rio de Janeiro, RJ, Brazil, 21945-970 D. Altbir Departamento de F´ısica, Universidad de Santiago de ...
arxiv
other
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null
true
true
false
cond-mat/0207368
Magnetism of carbon-based materials
[ "Makarova Tatiana " ]
We present a collection of experimental evidence on UFOs: Unidentified Ferromagnetic Organic structures. Five types of carbon magnets have been obtained experimentally: 1. Chains of interacting radicals 2. Carbonaceous substances with a mixture of sp2 and sp3 coordinated atoms 3. Amorphous carbon structures containin...
null
2002
2007-05-23 00:00:00
Magnetic Materials
null
http://arxiv.org/pdf/cond-mat/0207368v1
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null
To be published in*: Studies of High-Tc Superconductivity, vol. 44-45, Ed. by A. Narlikar.* # **MAGNETISM OF CARBON-BASED MATERIALS** #### **Tatiana Makarova** *Ioffe Physico-Technical Institute, St. Petersburg, Russia, Umeå University, Umeå, Sweden* E-mail: tatiana.makarova@physics.umu.se > For years there have be...
arxiv
other
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null
true
true
true
cond-mat/0209015
High Dielectric Permittivity in AFe$_{1 / 2}$B$_{1 / 2}$O$_{3}$ Nonferroelectric Perovskite Ceramics (A - Ba, Sr, Ca; B - Nb, Ta, Sb)
[ "Raevski I. P. ", "Prosandeev S. A. ", "Bogatin A. S. ", "Malitskaya M. A. " ]
AFe$_{1 / 2}$B$_{1 / 2}$O$_{3}$(A- Ba, Sr, Ca; B-Nb, Ta, Sb) ceramics were synthesized and temperature dependencies of the dielectric permittivity were measured at different frequencies. The experimental data obtained show very high values of the dielectric permittivity in a wide temperature interval that is inherent...
10.1063/1.1558205
2002
2009-11-07 00:00:00
Ceramics
null
http://arxiv.org/pdf/cond-mat/0209015v1
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# High Dielectric Permittivity in AFe<sup>1</sup>/<sup>2</sup>B<sup>1</sup>/<sup>2</sup>O<sup>3</sup> Nonferroelectric Perovskite Ceramics (A - Ba, Sr, Ca; B - Nb, Ta, Sb) I. P. Raevski<sup>1</sup>,<sup>2</sup> , S. A. Prosandeev<sup>1</sup>,<sup>3</sup> , A. S. Bogatin<sup>1</sup> , M. A. Malitskaya<sup>21</sup> <su...
arxiv
other
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null
true
true
true
cond-mat/0303369
Structural and Electronic Properties of Amorphous and Polycrystalline In2Se3 Films
[ "Chaiken A. ", "Nauka K. ", "Gibson G. A. ", "Lee Heon ", "Yang C. C. ", "Wu J. ", "Ager J. W. ", "Yu K. M. ", "Walukiewicz W. " ]
Structural and electronic properties of amorphous and single-phase polycrystalline films of gamma- and kappa-In2Se3 have been measured. The stable gamma phase nucleates homogeneously in the film bulk and has a high resistivity, while the metastable kappa phase nucleates at the film surface and has a moderate resistiv...
10.1063/1.1592631
2003
2009-11-10 00:00:00
Semiconductors
null
http://arxiv.org/pdf/cond-mat/0303369v1
null
null
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# Structural and Electronic Properties of Amorphous and Polycrystalline In2Se<sup>3</sup> Films A. Chaiken,[∗](#page-0-0) K. Nauka, G.A. Gibson, Heon Lee,[†](#page-0-1) and C.C. Yang Hewlett-Packard 1501 Page Mill Rd. Palo Alto, CA 94304 J. Wu, J.W. Ager, K.M. Yu, and W. Walukiewicz Materials Sciences Division Lawr...
arxiv
other
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null
true
true
true
cond-mat/0310078
Thermal degradation and viscoelasticity of polypropylene-clay nanocomposites
[ "Drozdov A. D. WVU", "Al-Mulla A. WVU", "Drozdov D. A. WVU", "Gupta R. K. WVU" ]
Results of torsional oscillation tests are reported that were performed at the temperature T=230C on melts of a hybrid nanocomposite consisting of isotactic polypropylene reinforced with 5 wt.% of montmorillonite clay. Prior to mechanical testing, specimens were annealed at temperatures ranging from 250 to 310C for v...
null
2003
2007-05-23 00:00:00
Composites
null
http://arxiv.org/pdf/cond-mat/0310078v1
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null
# Thermal degradation and viscoelasticity of polypropylene–clay nanocomposites A.D. Drozdov<sup>∗</sup> , A. Al-Mulla, D.A. Drozdov and R.K. Gupta Department of Chemical Engineering West Virginia University P.O. Box 6102 Morgantown, WV 26506, USA #### Abstract Results of torsional oscillation tests are reported that...
arxiv
other
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null
true
true
false
cond-mat/0310410
Oxygen Chemical Diffusion Coefficient in Manganite Thin Films by Isothermal Electric Resistivity Measurements
[ "Malavasi Lorenzo ", "Flor Giorgio " ]
In this paper we report the determination of oxygen diffusion coefficient for optimally doped manganite thin films of La0.85Na0.15MnO3 (LNMO). The study was performed by means of isothermal conductivity measurements on two different epitaxially oriented thin films grown on SrTiO3 (100) and SrTiO3 (110). The values fo...
null
2003
2007-05-23 00:00:00
Ceramics
null
http://arxiv.org/pdf/cond-mat/0310410v2
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# Oxygen Chemical Diffusion Coefficient in Manganite Thin Films by Isothermal Electric Resistivity Measurements *Lorenzo Malavasi\*a , and Giorgio Flor* a Dipartimento di Chimica Fisica "M. Rolla", INSTM, IENI/CNR Unità di Pavia of Università di Pavia, V.le Taramelli 16, I-27100, Pavia, Italy. \*E-mail: malavasi@chif...
arxiv
other
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null
true
true
true
cond-mat/0402012
Structural study of Cu$_{2-x}$Se alloys produced by mechanical alloying
[ "Machado K. D. ", "de Lima J. C. ", "Grandi T. A. ", "Gasperini A. A. M. ", "Maurmann C. E. ", "Souza S. M. ", "Campos C. E. M. ", "Pimenta A. F. " ]
The crystalline structures of superionic high temperature copper selenides Cu$_{2-x}$Se ($0 \le x \le 0.25$) produced by Mechanical Alloying were investigated using X-ray diffraction (XRD) technique. The measured XRD patterns showed the presence of the peaks corresponding to the crystalline superionic high temperatur...
10.1016/j.ssc.2005.09.006
2004
2009-11-10 00:00:00
Semiconductors
null
http://arxiv.org/pdf/cond-mat/0402012v1
null
null
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null
# Structural study of Cu2−xSe alloys produced by mechanical alloying J. C. de Lima, K. D. Machado <sup>∗</sup>, T. A. Grandi, A. A. M. Gasperini, C. E. Maurmann, S. M. Souza, C. E. M. Campos *Depto de F´ısica, Universidade Federal de Santa Catarina, Florian´opolis, Santa Catarina, Brazil, Cx. P. 476, 88040-900* A. F...
arxiv
other
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null
true
true
false
cond-mat/0404374
Photoemission studies of the annealing induced modifications of (Ga,Mn)As
[ "Adell M. 2 and 3", "Ilver L. 2 and 3", "Kanski J. 2 and 3", "Sadowski J. 2 and 3", "Mathieu R. " ]
Using angle resolved photoemission we have investigated annealing-induced changes in Ga(1-x)Mn(x)As with x = 0.05. We find that the position of the Fermi energy is a function of annealing time and temperature. It is also established that the Curie temperature is strongly correlated to the separation between the Fermi...
10.1103/PhysRevB.70.125204
2004
2009-11-10 00:00:00
Semiconductors
null
http://arxiv.org/pdf/cond-mat/0404374v1
null
null
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null
## Photoemission studies of the annealing induced modifications of (GaMn)As M. Adell, L. Ilver, and J. Kanski *Department of Experimental Physics, Chalmers University of Technology, SE-412 96 G¨oteborg, Sweden* J. Sadowski *MAX-lab, Lund University, SE-221 00 Lund, Sweden and* *Institute of Physics, Polish Academy...
arxiv
other
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null
true
true
false
cond-mat/0501377
Electronic structure of nanoscale iron oxide particles measured by scanning tunneling and photoelectron spectroscopies
[ "Preisinger M. ", "Krispin M. ", "Rudolf T. ", "Horn S. ", "Strongin D. R. " ]
We have investigated the electronic structure of nano-sized iron oxide by scanning tunnelling microscopy (STM) and spectroscopy (STS) as well as by photoelectron spectroscopy. Nano particles were produced by thermal treatment of Ferritin molecules containing a self-assembled core of iron oxide. Depending on the therm...
10.1103/PhysRevB.71.165409
2005
2009-11-11 00:00:00
Nanomaterials
null
http://arxiv.org/pdf/cond-mat/0501377v1
null
null
null
null
# Electronic structure of nanoscale iron oxide particles measured by scanning tunneling and photoelectron spectroscopies M. Preisinger,<sup>1</sup> M. Krispin,<sup>1</sup> T. Rudolf,<sup>1</sup> S. Horn,<sup>1</sup> and D. R. Strongin<sup>2</sup> 1 Institute of Physics, University of Augsburg, 86135 Augsburg, Germany...
arxiv
other
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null
true
true
false
cond-mat/0603702
Oxygen content variation and cation doping dependence of (La)1.4(Sr1-yCay)1.6Mn2O7 (y = 0, 0.25, 0.5) bilayered manganites properties
[ "Malavasi Lorenzo ", "Mozzati Maria Cristina ", "Tealdi Cristina ", "Azzoni Carlo B. ", "Flor Giorgio " ]
The results of the synthesis and characterization of the optimally doped (La)1.4(Sr1-yCay)1.6Mn2O7 solid solution with y=0, 0.25 and 0.5 are reported. By progressively replacing the Sr with the smaller Ca, while keeping fixed the hole-concentration due to the divalent dopant, the 'size effect' of the cation itself on...
10.1103/PhysRevB.74.064104
2006
2009-11-11 00:00:00
Ceramics
null
http://arxiv.org/pdf/cond-mat/0603702v1
null
null
null
null
# **OXYGEN CONTENT VARIATION AND CATION DOPING DEPENDENCE OF (La)1.4(Sr1-***y***Ca***y***)1.6Mn2O7±***δ* **(***y* **= 0, 0.25, 0.5) BILAYERED MANGANITES PROPERTIES** LORENZO MALAVASI a,\*, MARIA CRISTINA MOZZATI<sup>b</sup> , CRISTINA TEALDI a, CARLO B. AZZONI<sup>b</sup> , AND GIORGIO FLOR a *a Dipartimento di Chimi...
arxiv
other
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null
true
true
true
cond-mat/0603852
Large magnetic anisotropy in Ferrihydrite nanoparticles synthesized from reverse micelles
[ "Duarte E. L. ", "Itri R. ", "Lima E. Jr", "Baptista M. S. ", "Berquo T. S. ", "Goya G. F. " ]
Six-line ferrihydrite(FH) nanoparticles have been synthesized in the core of reverse micelles, used as nanoreactors to obtain average particle sizes $<d>$ $\approx$ 2 to 4 nm. The blocking temperatures $T_B^m$ extracted from magnetization data increased from $\approx 10$ to 20 K for increasing particle size. Low-temp...
10.1088/0957-4484/17/22/004
2006
2009-11-11 00:00:00
Nanomaterials
null
http://arxiv.org/pdf/cond-mat/0603852v2
null
null
null
null
# Large magnetic anisotropy in Ferrihydrite nanoparticles synthesized from reverse micelles E. L. Duarte, R. Itri, E. Lima Jr. *Instituto de F´isica, Universidade de S˜ao Paulo, CP 66318, S˜ao Paulo, 05315-970, Brazil* M. S. Baptista *Instituto de Qu´imica, Universidade de S˜ao Paulo, Av. Prof. Lineu Prestes 748, S˜...
arxiv
other
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null
true
true
true
cond-mat/0607488
Structural studies of thin films of semiconducting nanoparticles in polymer matrices
[ "Di Luccio T. ", "Piscopiello E. ", "Laera A. M. ", "Antisari M. Vittori " ]
We deposited thin layers of CdS and ZnS nanoparticles embedded in a thermoplastic cyclo-olephin copolymer (COC) with elevated optical transparency and highly bio-compatible. The nanoparticles were obtained by thiolate precursors previously dispersed in the polymer upon thermal treatment at temperatures ranging betwee...
null
2006
2007-05-23 00:00:00
Nanomaterials
null
http://arxiv.org/pdf/cond-mat/0607488v1
null
null
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null
# **Structural Studies of Thin Films of Semiconducting Nanoparticles in Polymer Matrices** *Tiziana Di Luccio,1,\* Emanuela Piscopiello,2 Anna Maria Laera,2 Marco Vittori Antisari <sup>3</sup>* > 1 ENEA, Centro Ricerche Portici, Via Vecchio Macello, I-80055 Portici (NA), Italy 2 ENEA, Centro Ricerche Brindisi, SS7 A...
arxiv
other
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null
true
true
false
cond-mat/0607584
RF Sputter Deposition of Epitaxial Nanocrystalline Nd1-xSrxCoO3 Thin Films
[ "Malavasi Lorenzo ", "Quartarone Eliana ", "Sanna Carla ", "Lampis Nathascia ", "Lehmann Alessandra Geddo ", "Tealdi Cristina ", "Mozzati Maria Cristina ", "Flor Giorgio " ]
In this paper we report the deposition of epitaxial thin films of Nd1-xSrxCoO3 with x=0, 0.2 and 0.5 on single crystalline substrates (SrTiO3 and LaAlO3) carried out by means of rf-magnetron sputtering. The deposited films are all completely oriented and epitaxial and characterized by a nanocrystalline morphology. As...
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2006
2007-05-23 00:00:00
Ceramics
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http://arxiv.org/pdf/cond-mat/0607584v1
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#### **Table of Contents Graphic** ![](_page_0_Figure_1.jpeg) 50 nm Nd0.5Sr0.5CoO3 thin film "as deposited" (A) and "annealed" (B) ### **Brief Summary** Single phase thin films of Nd1-*x*Sr*x*CoO3 (*x*=0, 0.2 and 0.5) perovskite with nanocrystalline morphology have been deposited on single crystalline substrates (S...
arxiv
other
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cond-mat/0610877
Quantitative AFM analysis of phase separated borosilicate glass surfaces
[ "Dalmas Davy SVI", "Lelarge Anne SVI", "Vandembroucq Damien SVI" ]
Phase separated borosilicate glass samples were prepared by applying various heat treatments. Using selective chemical etching we performed AFM measurement on the phase separated glass surfaces. A quantitative roughness analysis allowed us to measure precisely the dependence of the characteristic size of the phase do...
10.1016/j.jnoncrysol.2007.07.005
2006
2009-11-11 00:00:00
Ceramics
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http://arxiv.org/pdf/cond-mat/0610877v1
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# Quantitative AFM analysis of phase separated borosilicate glass surfaces D. Dalmas ∗, A. Lelarge and D. Vandembroucq *Laboratoire "Surface du Verre et Interfaces" Unit´e Mixte CNRS/Saint-Gobain 39 Quai Lucien Lefranc, 93303 Aubervilliers, France* #### Abstract Phase separated borosilicate glass samples were prepa...
arxiv
other
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cond-mat/0612200
Paramagnetic GaN:Fe and ferromagnetic (Ga,Fe)N - relation between structural, electronic, and magnetic properties
[ "Bonanni A. ", "Kiecana M. ", "Simbrunner C. ", "Li Tian ", "Sawicki M. ", "Quast M. Wegscheider. M. ", "Przybylinska H. ", "Navarro-Quezada A. ", "Wolos A. ", "Jantsch W. ", "Dietl T. " ]
We report on the metalorganic chemical vapor deposition (MOCVD) of GaN:Fe and (Ga,Fe)N layers on c-sapphire substrates and their thorough characterization via high-resolution x-ray diffraction (HRXRD), transmission electron microscopy (TEM), spatially-resolved energy dispersive X-ray spectroscopy (EDS), secondary-ion...
10.1103/PhysRevB.75.125210
2006
2009-09-29 00:00:00
Semiconductors
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http://arxiv.org/pdf/cond-mat/0612200v2
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# Paramagnetic GaN:Fe and ferromagnetic (Ga,Fe)N – relation between structural, electronic, and magnetic properties Alberta Bonanni,<sup>1</sup> Micha l Kiecana,<sup>2</sup> Clemens Simbrunner,<sup>1</sup> Tian Li,<sup>1</sup> Maciej Sawicki,<sup>2</sup> Matthias Wegscheider,<sup>1</sup> Martin Quast,<sup>1</sup> Han...
arxiv
other
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cond-mat/0701789
Recent advances in the internal functionalization of carbon nanotubes: synthesis, optical, and magnetic resonance studies
[ "Simon Ferenc ", "Pfeiffer Rudolf ", "Kuzmany Hans " ]
The hollow inside of single-wall carbon nanotubes (SWCNT) provides a unique degree of freedom to investigate chemical reactions inside this confined environment and to study the tube properties. It is reviewed herein, how encapsulating fullerenes, magnetic fullerenes, $^{13}$C isotope enriched fullerenes and organic ...
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2007
2007-05-23 00:00:00
Nanomaterials
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http://arxiv.org/pdf/cond-mat/0701789v2
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# Recent advances in the internal functionalization of carbon nanotubes: synthesis, optical, and magnetic resonance studies Ferenc Simon †, Rudolf Pfeiffer, and Hans Kuzmany Institut f¨ur Materialphysik, Universit¨at Wien Strudlhofgasse 4, A-1090 Wien, Austria ferenc.simon@univie.ac.at ### Abstract The hollow insid...
arxiv
other
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cond-mat/9906251
Oxygen Ordering Superstructures and Structural Phase Diagram of YBa_2Cu_3O_{6+x} Studied by Hard X-ray Diffraction
[ "Zimmermann M. v. ", "Frello T. ", "Andersen N. H. ", "Madsen J. ", "Käll M. ", "Schmidt O. ", "Niemöller T. ", "Schneider J. R. ", "Poulsen H. F. ", "Wolf Th. ", "Liang R. ", "Dosanjh P. ", "Hardy W. N. " ]
High energy x-ray diffraction is used to investigate the bulk oxygen ordering properties of YBa_2Cu_3O_{6+x}. Superstructures of Cu-O chains aligned along the b axis and ordered with periodicity ma, along the a axis have been observed. For $x < 0.62$ the only observed superstructure is ortho-II with m=2. At room temp...
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1999
2007-05-23 00:00:00
Superconductors
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http://arxiv.org/pdf/cond-mat/9906251v1
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# Oxygen Ordering Superstructures and Structural Phase Diagram of YBa2Cu3O6+<sup>x</sup> Studied by Hard X-ray Diffraction M. v. Zimmermann[∗](#page-11-0) Hamburger Synchrotronstrahlungslabor HASYLAB at Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, D-22603 Hamburg, Germany T. Frello, N. H. Andersen, J. Madsen...
arxiv
other
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